From Hydrophilic to Superhydrophobic: Fabrication of Micrometer-Sized Nail-Head-Shaped Pillars in Diamond

被引:57
作者
Karlsson, Mikael [1 ]
Forsberg, Pontus [1 ]
Nikolajeff, Fredrik [1 ]
机构
[1] Uppsala Univ, Dept Engn Sci, Angstrom Lab, SE-75121 Uppsala, Sweden
基金
瑞典研究理事会;
关键词
THIN-FILMS; SURFACES; BEHAVIOR;
D O I
10.1021/la902361c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrophobicity of microtextured diamond surfaces was investigated. Pillarlike structures were fabricated in both nanocrystalline diamond and microcrystalline diamond. By changing the surface termination of the textured diamond surface, We could switch between superhydrophobic surfaces and hydrophilic surfaces. Examined terminations were hydrogen, fluorine, and oxygen. To evaluate the wetting properties, advancing and receding contact angles were measured. By designing pillars with a wide diamond top on a narrower silicon stem, superhydrophobicity was achieved even when the advancing contact angle on the unstructured diamond surface was below 70 degrees. The possibility to manipulate the hydrophobicity and the Fresnel reflection simultaneously at an infrared wavelength is also demonstrated.
引用
收藏
页码:889 / 893
页数:5
相关论文
共 35 条
[1]   A novel ATR-FTIR approach for characterisation and identification of ex situ immobilised species [J].
Andersson, Per Ola ;
Lundquist, Margaretha ;
Teqler, Lotta ;
Borjejren, Susanne ;
Baltzer, Lars ;
Osterlund, Lars .
CHEMPHYSCHEM, 2007, 8 (05) :712-722
[2]   Purity of the sacred lotus, or escape from contamination in biological surfaces [J].
Barthlott, W ;
Neinhuis, C .
PLANTA, 1997, 202 (01) :1-8
[3]   Pearl drops [J].
Bico, J ;
Marzolin, C ;
Quéré, D .
EUROPHYSICS LETTERS, 1999, 47 (02) :220-226
[4]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[5]   Cell adhesion properties on photochemically functionalized diamond [J].
Chong, Kwok Feng ;
Loh, Kian Ping ;
Vedula, S. R. K. ;
Lim, Chwee Teck ;
Sternschulte, Hadwig ;
Steinmuller, Doris ;
Sheu, Fwu-shan ;
Zhong, Yu Lin .
LANGMUIR, 2007, 23 (10) :5615-5621
[6]   Experimental Investigation of the Band Broadening Arising from Short-Range Interchannel Heterogeneities in Chromatographic Beds under the Condition of Identical External Porosity [J].
Eghbali, Hamed ;
Verdoold, Vincent ;
Vankeerberghen, Lieselot ;
Gardeniers, Han ;
Desmet, Gert .
ANALYTICAL CHEMISTRY, 2009, 81 (02) :705-715
[7]   Origin of the 1150-cm-1 Raman mode in nanocrystalline diamond -: art. no. 121405 [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2001, 63 (12)
[8]   Water-repellent legs of water striders [J].
Gao, XF ;
Jiang, L .
NATURE, 2004, 432 (7013) :36-36
[9]   Protein-modified nanocrystalline diamond thin films for biosensor applications [J].
Härtl, A ;
Schmich, E ;
Garrido, JA ;
Hernando, J ;
Catharino, SCR ;
Walter, S ;
Feulner, P ;
Kromka, A ;
Steinmüller, D ;
Stutzmann, M .
NATURE MATERIALS, 2004, 3 (10) :736-742
[10]   Contact Line Pinning by Microfabricated Patterns: Effects of Microscale Topography [J].
Kalinin, Yevgeniy V. ;
Berejnov, Viatcheslav ;
Thorne, Robert E. .
LANGMUIR, 2009, 25 (09) :5391-5397