Surface active properties of chitosan and its derivatives

被引:173
作者
Elsabee, Maher Z. [1 ]
Morsi, Rania Elsayed [2 ]
Al-Sabagh, A. M. [3 ]
机构
[1] Cairo Univ, Fac Sci, Dept Chem, Cairo 12613, Egypt
[2] EPRI, Cent Lab, Nasr City 11727, Cairo, Egypt
[3] EPRI, Dept Petr Applicat, Nasr City 11727, Cairo, Egypt
关键词
Chitosan; Chitosan derivatives; Hydrophobic substitution; Surface active properties; Aggregation behavior; Drug encapsulation; Surface interactions; BY-LAYER ASSEMBLIES; POLYMERIC MICELLES; AIR-WATER; ALTERNATING BIOACTIVITY; PULMONARY SURFACTANT; HYDROPHILIC POLYMERS; PHOSPHOLIPID-BILAYER; AGGREGATION BEHAVIOR; GRAFTED CHITOSAN; MOLECULAR-WEIGHT;
D O I
10.1016/j.colsurfb.2009.06.021
中图分类号
Q6 [生物物理学];
学科分类号
071011 ;
摘要
This review discusses the definition of surface active agents and specifically natural polymeric Surface active agents. Chitosan by itself was found to have weak surface activity since it has no hydrophobic segments. Chemical modifications of chitosan could improve Such surface activity. This is achieved by introducing hydrophobic substituents in its glucosidic group. Several examples of chitosan derivatives with surfactant activity have been Surveyed. The surface active polymers form micelles and aggregates which have enormous importance in the entrapment of water-insoluble drugs and consequently applications in the controlled drug delivery and many biomedical fields. Chitosan also interacts with several substrates by electrostatic and hydrophobic interactions with considerable biomedical applications. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 16
页数:16
相关论文
共 106 条
[1]  
AIPING T, 2006, CARBOHYD POLYM, V66, P274
[2]   Demulsification efficiency of some novel styrene/maleic anhydride ester copolymers [J].
Al-Sabagh, A. M. ;
El-Din, M. R. Noor ;
Morsi, R. E. ;
Elsabee, M. Z. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 108 (04) :2301-2311
[3]   Electrostatic barrier to recovery of dipalmitoylphosphatidylglycerol monolayers after collapse [J].
Alig, TF ;
Warriner, HE ;
Lee, L ;
Zasadzinski, JA .
BIOPHYSICAL JOURNAL, 2004, 86 (02) :897-904
[4]   PYRENE FLUORESCENCE STUDY OF CHITOSAN SELF-ASSOCIATION IN AQUEOUS-SOLUTION [J].
AMIJI, MM .
CARBOHYDRATE POLYMERS, 1995, 26 (03) :211-213
[5]   SOLUTION PROPERTIES OF CHITOSANS - CONFORMATION AND CHAIN STIFFNESS OF CHITOSANS WITH DIFFERENT DEGREES OF N-ACETYLATION [J].
ANTHONSEN, MW ;
VARUM, KM ;
SMIDSROD, O .
CARBOHYDRATE POLYMERS, 1993, 22 (03) :193-201
[6]   Emulsion polymerization of vinyl acetate and styrene monomers in presence of polymeric surfactant [J].
Ayoub, MMH .
JOURNAL OF ELASTOMERS AND PLASTICS, 1998, 30 (03) :207-229
[7]   Synthesis and characterization of poly(aryl ether sulfone) PolyHIPE materials [J].
Cameron, NR ;
Sherrington, DC .
MACROMOLECULES, 1997, 30 (19) :5860-5869
[8]   RELATIONSHIPS BETWEEN THE CHAIN FLEXIBILITIES OF CHITOSAN MOLECULES AND THE PHYSICAL-PROPERTIES OF THEIR CASTED FILMS [J].
CHEN, RH ;
LIN, JH ;
YANG, MH .
CARBOHYDRATE POLYMERS, 1994, 24 (01) :41-46
[9]   Chemical characteristics of O-carboxymethyl chitosans related to the preparation conditions [J].
Chen, XG ;
Park, HJ .
CARBOHYDRATE POLYMERS, 2003, 53 (04) :355-359
[10]   Micellar enhanced ultrafiltration using PEO-PPO-PEO block copolymers [J].
Choi, YK ;
Lee, SB ;
Lee, DJ ;
Ishigami, Y ;
Kajiuchi, T .
JOURNAL OF MEMBRANE SCIENCE, 1998, 148 (02) :185-194