Shear melting in lyotropic hexagonal phases

被引:46
作者
Ramos, L [1 ]
Molino, F [1 ]
Porte, G [1 ]
机构
[1] Univ Montpellier 2, CNRS, Dynam Phases Condensees Grp, F-34095 Montpellier 5, France
关键词
D O I
10.1021/la000276k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We use small-angle X-ray scattering to investigate the structures under shear of surfactant hexagonal phases swollen with oil. Rheology studies of these materials indicate a shear-induced transition between two states of different viscosity. In the low shear regime, the cylinders are preferentially oriented along the flow and the hexagonal phase exhibits a polycrystalline texture. Unexpectedly, a high shear has the effect of melting the long-range two-dimensional (2D) order of the cylinders, leading to a 2D liquid of cylinders strongly aligned along the flow.
引用
收藏
页码:5846 / 5848
页数:3
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