MCM-41-supported phosphotungstic acid-catalyzed cleavage of C-O bond in allyl aryl ethers

被引：14

作者：

Sakate, Sachin S. ^{[1
,2
]}

Kamble, Sumit B. ^{[1
]}

Chikate, Rajeev C. ^{[3
]}

Rode, Chandrashekhar V. ^{[1
]}

机构：

[1] CSIR, Natl Chem Lab, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India

[2] PE Soc Modern Coll Arts Sci & Commerce, Pune 411005, Maharashtra, India

[3] ME Soc Abasaheb Garware Coll, Karve Rd, Pune 411004, Maharashtra, India

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 12期

关键词：

CARBOHYDRATE-CHEMISTRY; SELECTIVE CLEAVAGE; PROTECTING GROUP; DODECATUNGSTOPHOSPHORIC ACID; REDUCTIVE DEPROTECTION; SAMARIUM(II) IODIDE; NEUTRAL CONDITIONS; MOLECULAR-SIEVES; TERT-BUTYLATION; ALCOHOLS;

D O I：

10.1039/c7nj00375g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Removal of the protecting allyl group from allyl aryl ethers in the presence of other oxygen protecting groups was successfully achieved using a solid acid supported on the high surface area material MCM-41. The catalyst showed excellent activity in the presence of various electron withdrawing, electron donating, and oxidizable functional groups. The methodology is also very useful for the removal of protecting allyl groups of various natural products such as vanillin, isovanillin, and other oxygen functionalized aldehydes and ketones.

引用

页码：4943 / 4949

页数：7

共 22 条

[21] Palladium/Acid-Catalyzed Straightforward Allylation of Arenes using 1-Substituted Propynes via Aryl C-H Bond Activation [J].

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ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (07) :1343-1346

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Suga, Takuya ;

Kondo, Miki ;

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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2024, 97 (02)

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