Interaction with olefins of the partially polarized surface of silver nanoparticles activated by p-benzoquinone and its implications for facilitated olefin transport

被引:94
作者
Kang, Yong Soo [1 ]
Kang, Sang Wook
Kim, Hosub
Kim, Jong Hak
Won, Jongok
Kim, Chang Kon
Char, Kookheon
机构
[1] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
[2] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151744, South Korea
[3] Yonsei Univ, Dept Chem Engn, Seoul 120749, South Korea
[4] Sejong Univ, Dept Appl Chem, Seoul 143747, South Korea
[5] Inha Univ, Dept Chem, Inchon 402751, South Korea
关键词
D O I
10.1002/adma.200601009
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Silver nanoparticles activated by electron acceptors, such as p-benzoquinone, are used as olefin carriers for facilitated olefin transport. Poly(ethylene-co-propylene) (EPR)-Ag-0-p-benzoquinone (p-BQ) membranes show good separation performance of propylene-propane mixtures over periods longer than 100 hours. The ideal separation factor through 1:1:XEPR/Ag-0/P-BQ membranes with varying weight ratios of p-BQ to EPR is shown in the figure.
引用
收藏
页码:475 / +
页数:6
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