Copolymers of Diallyldimethylammonium Chloride and Vinyl Ether of Monoethanolamine: Synthesis, Flocculating, and Antimicrobial Properties

被引:15
作者
Dauletov, Yerbol [1 ,2 ]
Nuraje, Nurxat [2 ]
Abdiyev, Kaldibek [1 ]
Toktarbay, Zhexenbek [3 ]
Zhursumbaeva, Maryamgul [1 ]
机构
[1] Kazakh Natl Tech Res Univ, Dept Chem Technol Organ Cpds & Polymers, 22 Satpaev Str, Alma Ata 050013, Kazakhstan
[2] Texas Tech Univ, Dept Chem Engn, Lubbock, TX 79409 USA
[3] Al Farabi Kazakh Natl Univ, Dept Analyt Colloidal Chem & Technol Rare Element, Fac Chem & Chem Technol, Al Farabi Ave 71, Alma Ata 050012, Kazakhstan
关键词
Radical copolymerization; Flocculation; Antimicrobial activity; Sulfate-reducing bacteria; RADIATION-INDUCED POLYMERIZATION; BENIGN INITIATING SYSTEM; CATIONIC-POLYMERIZATION; N; N-DIALLYL-N; N-DIMETHYLAMMONIUM CHLORIDE; RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; POLYMERS; AMMONIUM; KINETICS;
D O I
10.1002/jsde.12283
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
N,N-diallyl-N,N-dimethylammonium chloride (DADMAC) and vinyl ether of monoethanolamine (VEMEA) copolymer P(DADMAC-VEMEA) were synthesized using radical polymerization in water media using ammonium persulfate as an initiator. The synthesis of this copolymer was investigated over a wide composition range at low conversion levels. The viscosity of the copolymers was measured in aqueous 1 M NaCl. Flocculating action and antimicrobial activities of the copolymers P(DADMAC-VEMEA) against microbacteria and sulfate-reducing bacteria (SRB) were studied. Synthesized copolymers had flocculating effects and can be used to purify wastewater from particles of bentonite clays. Also, the copolymer with a molar composition [DADMAC]: [VEMEA] = (80 divided by 20):(20 divided by 80) retarded the population of both bacteria, Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) in the diffusion zone. Furthermore, the copolymer with a molar composition [DADMAC]:[VEMEA] = (90 divided by 10):(20 divided by 80) had bactericidal properties against SRB. Minimum inhibitory concentration (MIC) of the copolymer varied from 0.01% to 0.1% depending on the molar composition of the copolymer.
引用
收藏
页码:1129 / 1137
页数:9
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