Bis(2,2′-bipyridine-κ2N,N′)dibromidocadmium(II)

被引：3

作者：

Zhang, Bi-Song ^{[1
]}

机构：

[1] Jinhua Coll Profess & Technol, Coll Mat Sci & Chem Engn, Jinhua 321017, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

D O I：

10.1107/S1600536809042597

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex molecule, [CdBr2(C10H8N2)(2)], the Cd-II ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,2 '-bipyridine ligands in a distorted octahedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)degrees. In the crystal packing, pi-pi stacking interactions [centroid-centroid distances = 3.837 (6) and 3.867 (11) angstrom] link adjacent complex molecules into chains running parallel to the b axis. The chains are further connected by intermolecular C-H center dot center dot center dot Br hydrogen bonds into a three-dimensional network.

引用

页码：M1413 / U1559

页数：10