Carboxylative cyclization of propargylic amines with CO2 catalyzed by dendritic N-heterocyclic carbene-gold(I) complexes

被引：43

作者：

Fujita, Ken-ichi ^{[1
]}

Inoue, Kensuke ^{[2
]}

Sato, Junichi ^{[3
]}

Tsuchimoto, Teruhisa ^{[2
]}

Yasuda, Hiroyuki ^{[1
,3
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba Cent 5,1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan

[2] Meiji Univ, Dept Appl Chem Sch Sci & Technol, Tama Ku, Kanagawa 2148571, Japan

[3] Ibaraki Univ, Grad Sch Sci & Engn, 2-1-1 Bunkyo, Ibaraki 3108512, Japan

来源：

TETRAHEDRON | 2016年 / 72卷 / 09期

关键词：

NHC-gold(I) complex; Carbon dioxide; Propargylic amine; 2-Oxazolidinone; MIYAURA COUPLING REACTION; ARYL ETHER DENDRIMERS; CARBON-DIOXIDE; CHEMICAL-YIELD; AQUEOUS-MEDIA; DIELS-ALDER; OXAZOLIDINONES; LIGANDS; FIXATION; BEARING;

D O I：

10.1016/j.tet.2016.01.016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We prepared several of a new type of dendritic N-heterocyclic carbene (NHC)-gold(I) complex. In particular, by employing an amphiphilic dendritic NHC-gold(I) complex having penta(ethylene glycol) units at the peripheral layer as a catalyst, the aqueous media carboxylative cyclization of propargylic amines proceeded smoothly to provide the corresponding 2-oxazolidinone at room temperature under atmospheric pressure of CO2. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：1205 / 1212

页数：8