Carboxylative cyclization of propargylic amines with CO2 catalyzed by dendritic N-heterocyclic carbene-gold(I) complexes

被引：42
|
作者：
Fujita, Ken-ichi [1 ]
Inoue, Kensuke [2 ]
Sato, Junichi [3 ]
Tsuchimoto, Teruhisa [2 ]
Yasuda, Hiroyuki [1 ,3 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba Cent 5,1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan
[2] Meiji Univ, Dept Appl Chem Sch Sci & Technol, Tama Ku, Kanagawa 2148571, Japan
[3] Ibaraki Univ, Grad Sch Sci & Engn, 2-1-1 Bunkyo, Ibaraki 3108512, Japan
来源：
TETRAHEDRON | 2016年 / 72卷 / 09期
关键词：
NHC-gold(I) complex; Carbon dioxide; Propargylic amine; 2-Oxazolidinone; MIYAURA COUPLING REACTION; ARYL ETHER DENDRIMERS; CARBON-DIOXIDE; CHEMICAL-YIELD; AQUEOUS-MEDIA; DIELS-ALDER; OXAZOLIDINONES; LIGANDS; FIXATION; BEARING;
D O I：
10.1016/j.tet.2016.01.016
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We prepared several of a new type of dendritic N-heterocyclic carbene (NHC)-gold(I) complex. In particular, by employing an amphiphilic dendritic NHC-gold(I) complex having penta(ethylene glycol) units at the peripheral layer as a catalyst, the aqueous media carboxylative cyclization of propargylic amines proceeded smoothly to provide the corresponding 2-oxazolidinone at room temperature under atmospheric pressure of CO2. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1205 / 1212
页数：8
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