Dynamic behavior of confined branched hydrocarbon lubricant fluids under shear

被引:86
作者
Drummond, C
Israelachvili, J [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/ma9919918
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We have measured the friction forces between molecularly smooth mica surfaces confining thin films of different branched hydrocarbons, using the surface forces apparatus (SFA). The evolution of the systems to steady-state sliding from rest or after a change in sliding velocity was thoroughly studied, and the presence of different length and time scales was observed. Using a new "extended bimorph slider" which allows continuous shearing for distances well beyond the contact diameter, we show that the evolution to steady-state sliding in these films is governed by the distance the surfaces are sheared rather than the time. From these results it is clear that both time and distance of sliding have to be considered in order to fully describe the dynamic response of lubricants and complex fluids under shear.
引用
收藏
页码:4910 / 4920
页数:11
相关论文
共 39 条
[1]  
BAJON ARC, 1997, MICRO NANOTRIBOLOGY
[2]  
BATISTA AA, COMMUNICATION
[3]   CROSSOVER FROM CREEP TO INERTIAL MOTION IN FRICTION DYNAMICS [J].
BAUMBERGER, T ;
HESLOT, F ;
PERRIN, B .
NATURE, 1994, 367 (6463) :544-546
[4]   Origin and characterization of different stick-slip friction mechanisms [J].
Berman, AD ;
Ducker, WA ;
Israelachvili, JN .
LANGMUIR, 1996, 12 (19) :4559-4563
[5]   Physical analysis of the state- and rate-dependent friction law: Static friction [J].
Berthoud, P ;
Baumberger, T ;
G'Sell, C ;
Hiver, JM .
PHYSICAL REVIEW B, 1999, 59 (22) :14313-14327
[6]   TIME-DEPENDENCE OF STATIC FRICTION [J].
BROCKLEY, CA ;
DAVIS, HR .
JOURNAL OF LUBRICATION TECHNOLOGY, 1968, 90 (01) :35-&
[7]  
Carlson J., UNPUB
[8]   Critique of the friction coefficient concept for wet (lubricated) sliding [J].
Dhinojwala, A ;
Cai, L ;
Granick, S .
LANGMUIR, 1996, 12 (19) :4537-4542
[9]   TIME-DEPENDENT FRICTION AND MECHANICS OF STICK-SLIP [J].
DIETERICH, JH .
PURE AND APPLIED GEOPHYSICS, 1978, 116 (4-5) :790-806
[10]  
DOWSON D, 1979, HISTORY TRIBOLOGY