New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

被引：73
作者：
Jones, LF
Brechin, EK
Collison, D
Harrison, A
Teat, SJ
Wernsdorfer, W
机构：
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[2] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[3] CLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England
[4] CNRS, Lab Louis Neel, F-38042 Grenoble 9, France
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 24期
关键词：
D O I：
10.1039/b209445b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)(10)(OMe)(6)(F)(10)(BTA)(20)(BTAH)(2)(MeOH)(13)(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.
引用
收藏
页码：2974 / 2975
页数：2
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