Effect of Modified Nanoclay Surface Supported Nickel Catalyst on Carbon Dioxide Reforming of Methane

被引:3
|
作者
Chaisamphao, Juthasiri [1 ]
Kiatphuengporn, Sirapassorn [2 ]
Faungnawakij, Kajornsak [2 ]
Donphai, Waleeporn [3 ,4 ]
Chareonpanich, Metta [3 ,4 ]
机构
[1] Kasetsart Univ, Interdisciplinary Grad Program Sustainable Energy, Bangkok, Thailand
[2] Natl Sci & Technol Dev Agcy NSTDA, Natl Nanotechnol Ctr NANOTEC, Pathum Thani, Thailand
[3] Kasetsart Univ, Fac Engn, Dept Chem Engn, Bangkok, Thailand
[4] Res Network NANOTEC KU NanoCatalysts & NanoMat Su, Bangkok, Thailand
关键词
Nanoclay; Nickel; Dry reforming reaction; Modification; Hydrogen; NI-BASED CATALYSTS; NATURAL CLAY; MONTMORILLONITE; NANOCOMPOSITES; PEROVSKITES; PROMOTION; HYDROGEN; CATION; GAS; XRD;
D O I
10.1007/s11244-020-01403-y
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The activity and stability of modified nanoclays surface supported nickel (Ni/NC-x) catalyst were investigated and compared to unmodified nanoclay surface supported nickel (Ni/NC) catalyst in dry reforming reaction (500-800 degrees C). The nickel metal was loaded on modified nanoclay surface with different alkylammonium modifiers-trimethylstearyl ammonium (NC-T), methyl dihydroxy-ethyl hydrogenated tallow ammonium (NC-M), aminopropyltriethoxysilane and octadecylamine (NC-A), and dimethyl dialkyl amine (NC-D) by using the impregnation method. As a results, the surface area and pore volume of Ni/NC-x catalysts were 1.70-3.96 and 2.33-4.33 times higher than that of Ni/NC catalyst, respectively. A longer chain of alkylammonium ions of modifier enhanced the intercalation of the modifier molecules into the interlayer of the nanoclay. Among these catalysts, the highest surface area of Ni/NC-T catalyst could facilitate the Ni metal dispersion and smaller size of NiO, resulting in the stronger interaction between Ni and NC-T support. It then gave the highest CO2 and CH4 conversions and H-2/CO ratio. In addition, H-2 and CO yields of Ni/NC-T catalyst were 1.21 and 1.20 times higher than that of Ni/NC catalyst, respectively. Moreover, the modified nanoclays surface supported nickel catalyst could reduce the carbon formation during the reaction.
引用
收藏
页码:431 / 445
页数:15
相关论文
共 50 条
  • [11] Carbon Dioxide Reforming of Methane over Nickel Catalyst Supported on MgO(111) Nanosheets
    Luming Zhang
    Lin Li
    Jinlin Li
    Yuhua Zhang
    Juncheng Hu
    Topics in Catalysis, 2014, 57 : 619 - 626
  • [12] Study on the reaction mechanism for carbon dioxide reforming of methane over supported nickel catalyst
    Qian, L
    Yan, ZF
    CHINESE CHEMICAL LETTERS, 2003, 14 (10) : 1081 - 1084
  • [13] Activation of supported nickel catalysts for carbon dioxide reforming of methane
    Souza, MD
    Clavé, L
    Dubois, V
    Perez, CAC
    Schmal, M
    APPLIED CATALYSIS A-GENERAL, 2004, 272 (1-2) : 133 - 139
  • [14] Catalytic performance of modified Vermiculite-supported Nickel in Methane dry Reforming with carbon dioxide
    Mahir, Hanane
    Mesrar, Farah
    Ouanji, Fatiha
    Kacimi, Mohamed
    Ziyad, Mahfoud
    Liotta, Leonarda F.
    PROCEEDINGS OF 2019 7TH INTERNATIONAL RENEWABLE AND SUSTAINABLE ENERGY CONFERENCE (IRSEC), 2019, : 713 - 717
  • [15] Effect of alkaline earth metal oxide on nickel catalyst for carbon dioxide reforming of methane
    Jung, K.S.
    Moon, H.-D.
    Lee, H.-I.
    Research on Chemical Intermediates, 2000, 26 (1 pt 1) : 45 - 53
  • [16] The effect of alkaline earth metal oxide on nickel catalyst for carbon dioxide reforming of methane
    K. S. Jung
    H. -D. Moon
    H. -I. Lee
    Research on Chemical Intermediates, 2000, 26 : 45 - 53
  • [17] The effect of alkaline earth metal oxide on nickel catalyst for carbon dioxide reforming of methane
    Jung, KS
    Moon, HD
    Lee, HI
    RESEARCH ON CHEMICAL INTERMEDIATES, 2000, 26 (01) : 45 - 53
  • [18] Zeolite-supported Ni catalyst for methane reforming with carbon dioxide
    P. Frontera
    A. Aloise
    A. Macario
    F. Crea
    P. L. Antonucci
    G. Giordano
    J. B. Nagy
    Research on Chemical Intermediates, 2011, 37 : 267 - 279
  • [19] Methane reforming with carbon dioxide over supported nickel catalysts.
    Schmitz, AD
    Yoshida, T
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 43 - PETR
  • [20] CARBON-DIOXIDE REFORMING OF METHANE ON SUPPORTED NICKEL-CATALYSTS
    TAKANO, A
    TAGAWA, T
    GOTO, S
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1994, 27 (06) : 727 - 731