Modelling study of boundary-layer ozone over northern China - Part II: Responses to emission reductions during the Beijing Olympics

The implementation of emission reduction measures during the Olympics provided a valuable opportunity to study regional photochemical pollution over northern China. In this study, the fifth-generation Pennsylvania State University/National Centre for Atmospheric Research Mesoscale Model and Community Multiscale Air Quality model system was applied to conduct two sets of modelling analyses of the period from July 20 to September 20, 2008, to illustrate the influences of emission reduction measures on regional photochemical pollution over northern China during the Beijing Olympics. The results indicated that the implementation of emission control measures decreased the concentrations of ozone (O-3) precursors, namely nitrogen oxide (NOx) and volatile organic compounds (VOCs), throughout the boundary layer. The concentrations of these compounds were reduced by 45% in the central urban area of Beijing at the ground level. Although the average O3 concentration in the central urban area increased by more than 8 ppbv, the total oxidant concentration decreased significantly by more than 5 ppbv. Greater O-3 concentrations mainly occurred during periods with weak photochemical reactions. During periods of strong photochemical production, the O3 concentration decreased significantly due to a weakening vertical circulation between the lower and upper boundary layer. Consequently, the number of days when the O-3 concentration exceeded 100 ppbv decreased by 25% in Beijing. The emission control measures altered the sensitivity of the regional O-3 production. The coordinated control region of NOx and VOCs expanded, and the control region-of VOCs decreased in size. The reduction of non-point-source emissions, such as fugitive VOCs and vehicles, was more useful for controlling regional photochemical pollution over northern China. (C) 2017 Elsevier B.V. All rights reserved.