A novel method for the chemoselective reduction of azides to amines with a Sm/CoCl2•6H2O system

被引：0

作者：

Wu, HY ^{[1
]}

Chen, R ^{[1
]}

Zhang, YM ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2000年 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Azides can be easily reduced to the corresponding amines with Sm/CoC1(2) . 6H(2)O in excellent yields under mild and neutral conditions.

引用

页码：248 / 249

页数：2

共 19 条

[11] REACTION OF AZIDES WITH TETRATHIOMOLYBDATE - REDUCTION AND IMINE FORMATION [J].

RAMESHA, AR ;

BHAT, S ;

CHANDRASEKARAN, S .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (23) :7682-7683

[12] REDUCTION OF AZIDES WITH ZINC BOROHYDRIDE [J].

RANU, BC ;

SARKAR, A ;

CHAKRABORTY, R .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (15) :4114-4116

[13]

SANDLER SR, 1971, ORGANIC FUNCTIONAL G, V2, P266

[14]

SHERADSKY T, 1971, CHEM AZIDO GROUP, pCH6

[15] ELECTRONIC CHARACTER OF AZIDO GROUP ATTACHED TO BENZENE RINGS [J].

SMITH, PAS ;

HALL, JH ;

KAN, RO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (03) :485-&

[16] SOME ORGANIC-REACTIONS PROMOTED BY SAMARIUM DIIODIDE [J].

SOUPPE, J ;

DANON, L ;

NAMY, JL ;

KAGAN, HB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :227-236

[17]

BEILSTEINS HDB ORGAN, V12, P687

[18]

BEILSTEINS HDB ORGAN, V9, P587

[19]

1996, ALDRICH

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