Trichloroisocyanuric acid, as an industrial chemical, promotes transthioacetalization of diacetals of 2,2-bis (hydroxymethyl)-1,3-propanediol and cleavage of thioacetals

被引：8

作者：

Firouzabadi, H ^{[1
]}

Iranpoor, N ^{[1
]}

Hazarkhani, H ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2002年 / 177卷 / 11期

关键词：

deprotection; diacetals of 2,2-bis (hydroxymethyl)-1,3-propanediol; transthioacetalization; thioacetals; trichloroisocyanuric acid;

D O I：

10.1080/10426500214566

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trichloroisocyanuric acid has been used as a mild, efficient, and new catalyst for transthioacetalization of diacetals of 2,2-bis (hydroxymethyl)-1,3-propanediol in CH2Cl2 at room temperature. A clean, easy, and general method for efficient deprotection of thioacetals to their corresponding carbonyl compounds using trichloroisocyanuric acid/silica gel and water system also is described.

引用

页码：2571 / 2577

页数：7

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