Homogeneous nanosize palladium catalysts

被引：72

作者：

Tsuji, Yasushi ^{[1
]}

Fujihara, Tetsuaki ^{[1
]}

机构：

[1] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Sch Engn, Kyoto 6158510, Japan

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 06期

关键词：

CROSS-COUPLING REACTIONS; PD BLACK FORMATION; PALLADIUM(II)-CATALYZED OXIDATION; AIR OXIDATION; COMPLEXES; ALCOHOLS; ARYL; NANOFILTRATION; HYDROGENATION; NANOPARTICLES;

D O I：

10.1021/ic061872q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Expanding the catalytic environment to a nanosize must be one of the most promising ways to improve the performance of homogeneous catalysts. In this Forum Article, recent developments in homogeneous nanosize palladium catalysts are reviewed. It contains solubilized palladium nanoparticles, metalated dendrimers, and complexes with well-defined nanosized ligands. These systems realize efficient catalyst recycling, unique selectivity, suppression of metal aggregation, and remarkable enhancement of the catalytic activity.

引用

页码：1895 / 1902

页数：8

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