Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, β-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21]

被引：10

作者：

Jayasundera, Anil C. A. ^{[1
]}

Goff, Richard J. ^{[1
]}

Li, Yang ^{[1
]}

Finch, Adrian A. ^{[2
]}

Lightfoot, Philip ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStChem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ St Andrews, Sch Geog & Geosci, St Andrews KY16 9AL, Fife, Scotland

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

Solvothermal synthesis; Indium fluoride; Chiolite; Cryalite; Hybrid material; SCANDIUM FLUORIDE; PHASE-TRANSITIONS; PEROVSKITES; OCTAHEDRA; ELPASOLITES; SYSTEM;

D O I：

10.1016/j.jssc.2009.11.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal syntheses and crystal structures of three indium fluorides are presented. K5In3F14 (1) and beta-(NH4)(3)InF6 (2) are variants on known inorganic structure types chiolite and cryolite, respectively, with the latter exhibiting a complex and apparently novel structural distortion. [NH4](3)[C6H21N4](2) [In4F21] (3) represents a new hybrid composition displaying a unique trimeric metal fluoride building unit. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：356 / 360

页数：5

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