The rhodium-catalysed 1,2-addition of arylboronic acids to aldehydes and ketones with sulfonated S-Phos

被引：30

作者：

White, James R. ^{[1
]}

Price, Gareth J. ^{[1
]}

Plucinski, Pawel K. ^{[2
]}

Frost, Christopher G. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Bath, Dept Chem Engn, Bath BA2 7AY, Avon, England

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 52期

基金：

英国工程与自然科学研究理事会;

关键词：

CROSS-COUPLING REACTIONS; ALKENYLBORONIC ACIDS; ASYMMETRIC ADDITION; AQUEOUS SOLVENTS; SUZUKI-MIYAURA; BORONIC ACIDS; LIGANDS; WATER; COORDINATION; REACTIVITY;

D O I：

10.1016/j.tetlet.2009.10.082

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium-catalysed 1,2-addition of arylboronic acids to aryl aldehydes has been accomplished in high yield using sulfonated S-Phos, a water-soluble biaryl phosphine ligand which allows for catalyst recycling. The catalytic protocol has also been successful in the challenging arylation of ketones. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：7365 / 7368

页数：4

共 32 条

[31] 1,4-Addition of arylboronic acids to β-aryl-α,β-unsaturated ketones and esters catalyzed by a rhodium(I)-chiraphos complex for catalytic and enantioselective synthesis of selective endothelin -: A receptor antagonists
Itoh, Takahiro
Mase, Toshiaki
Nishikata, Takashi
Iyama, Tetsuji
Tachikawa, Hiroto
Kobayashi, Yuri
Yarnamoto, Yasunori
Miyaura, Norio
TETRAHEDRON, 2006, 62 (41) : 9610 - 9621
[32] 1,2-ADDITION OF ALKYLZIRCONOCENE AND ALKENYLZIRCONOCENE CHLORIDES TO ALDEHYDES ACCELERATED BY CATALYTIC AMOUNTS OF ZNBR2 AS A METHOD OF SYNTHESIZING SECONDARY ALCOHOLS, SECONDARY ALLYLIC ALCOHOLS, AND IN-SITU OPPENAUER-TYPE OXIDATION OF THE ALCOHOLS TO KETONES
ZHENG, B
SREBNIK, M
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (11): : 3278 - 3279

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