NiCoCrAlY coatings with and without an Al2O3/Al interlayer on an orthorhombic Ti2AlNb-based alloy:: Oxidation and interdiffusion behaviors

被引：93

作者：

Wang, Q. M. ^{[1
]}

Zhang, K. ^{[1
]}

Gong, J. ^{[1
]}

Cui, Y. Y. ^{[1
]}

Sun, C. ^{[1
]}

Wen, L. S. ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Div Surface Engn Mat, Shenyang 110016, Peoples R China

来源：

ACTA MATERIALIA | 2007年 / 55卷 / 04期

基金：

中国国家自然科学基金;

关键词：

titanium aluminide; NiCoCrAlY coating; oxidation; interdiffusion; diffusion barrier;

D O I：

10.1016/j.actamat.2006.09.044

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The mechanism of oxidation protection of NiCoCrAlY overlay coatings on the orthorhombic Ti(2)AINb-based alloy (O alloy) Ti-22Al-26Nb (at.%) is described. While the bare alloy exhibited poor oxidation resistance at 800 degrees C, adding NiCoCrAlY coatings significantly improved the oxidation resistance. However, serious interdiffusion between the coatings and the substrate resulted in rapid degradation of the coating system. Several reaction layers were formed at the coating/substrate interface by interdiffusion, and nonprotective scales mainly of Cr2O3 and TiO2 were formed due to the degradation of the coating. In order to solve this problem, an Al2O3/Al interlayer was sandwiched into the coating system as a diffusion barrier. The isothermal and cyclic oxidation protection of the multilayer coating system on the Ti-22Al-26Nb substrate was evaluated at 800 and 900 degrees C. The results indicated that the interdiffusion was much suppressed, and the duplex coating system demonstrated improved oxidation resistance on the Ti-22Al-26Nb substrate, with a thin and adherent protective alpha-Al2O3 scale forming on the surface. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页码：1427 / 1439

页数：13

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