Cyclophosphazene-based multi-site coordination ligands

被引：170

作者：

Chandrasekhar, Vadapalli ^{[1
]}

Thilagar, Pakkirisamy ^{[1
]}

Pandian, Balasubramanian Murugesa ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 9-10期

关键词：

cyclophosphazenes; cyclophosphazene ligands; multi-site coordination ligands; polymeric ligands; aminocyclophosphazenes; metal complexes; heterobimetallic complexes;

D O I：

10.1016/j.ccr.2006.07.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review deals with the recent developments in the design, assembly and utility of cyclophosphazene-based ligands. The reactive periphery of the chlorocyclophosphazenes allows their ready elaboration into a variety of multi-site coordination ligands such as pyrazolylcyclophosphazenes, cyclophosphazene hydrazides, pyridyloxycyclophosphazenes, pyridylaminocyclophosphazenes, phosphine-containing cyclophosphazenes, etc. The versatile coordination behavior of these diverse ligand systems is described. The extension of the small-molecule chemistry to the more complex polymer systems, which has been done in a few systems, is described. The utility of aminocyclophosphazenes for preparing multi-metallic architectures is also discussed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1045 / 1074

页数：30

共 138 条

[81]

KRISHNAMURTHY SS, 1978, ADV INORG CHEM, V21, P41

[82]

Krummenacher I, 2006, DALTON T, P1073, DOI 10.1039/b512309g

[83] A monovalent gallium complex supported by tris(3,5-di-tert-butylpyrazolyl)hydroborato ligation: The syntheses and structures of [TpBu(2)(t)]Ga and its GaI3 adduct, [TpBu(2)(t)]Ga->GaI31 [J].

Kuchta, MC ;

Bonanno, JB ;

Parkin, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (44) :10914-10915

[84]

Lawson GT, 1999, EUR J INORG CHEM, P1881

[85] cis-Trihydrogen cyclotriphosphazenates-acidic anions in strongly basic media [J].

Lawson, GT ;

Rivals, F ;

Tascher, M ;

Jacob, C ;

Bickley, JF ;

Steiner, A .

CHEMICAL COMMUNICATIONS, 2000, (05) :341-342

[86] OPTICALLY-ACTIVE AND C3-SYMMETRICAL TRIS(PYRAZOLYL)HYDROBORATE AND TRIS(PYRAZOLYL)PHOSPHINE OXIDE LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION [J].

LECLOUX, DD ;

TOKAR, CJ ;

OSAWA, M ;

HOUSER, RP ;

KEYES, MC ;

TOLMAN, WB .

ORGANOMETALLICS, 1994, 13 (07) :2855-2866

[87] Reactions of a Ru(II) phenyl complex with substrates that possess C-N or C-O multiple bonds: C-C bond formation, N-H bond cleavage, and decarbonylation reactions [J].

Lee, JP ;

Pittard, KA ;

DeYonker, NJ ;

Cundari, TR ;

Gunnoe, TB ;

Petersen, JL .

ORGANOMETALLICS, 2006, 25 (06) :1500-1510

[88] BEITRAGE ZUR FRAGE DER SUBSTITUTION AN PHOSPHORNITRIDCHLORIDEN .I. ZUR AMMONOLYSE DES TRIMEREN PHOSPHORNITRIDCHLORIDS [J].

LEHR, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1967, 350 (1-2) :18-&

[89]

Mahalakshmi L, 2002, STRUCT BOND, V103, P85

[90] HETEROCYCLIC-COMPOUNDS CONTAINING PHOSPHORUS .29. SYNTHESIS AND STUDY OF ACYCLIC AND CYCLIC PHOSPHORETED COMPOUNDS DERIVED FROM HYDRAZINES [J].

MAJORAL, JP ;

KRAEMER, R ;

NAVECH, J ;

MATHIS, F .

TETRAHEDRON, 1976, 32 (21) :2633-2644

← 4 5 6 7 8 9 10 11 12 13 →