CuX2-mediated [4+2] benzannulation as a new synthetic tool for stereoselective construction of haloaromatic compounds

被引：51

作者：

Isogai, Yukie ^{[1
]}

Menggenbateer ^{[1
]}

Khan, F. Nawaz ^{[1
]}

Asao, Naoki ^{[1
,2
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Grad Sch Sci, Res & Analyt Ctr Giant Mol, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON | 2009年 / 65卷 / 46期

关键词：

C-H BONDS; THIN-FILM TRANSISTORS; ORGANIC SEMICONDUCTORS; SUBSTITUTED NAPHTHALENES; CATALYZED BENZANNULATION; TETRACENE DERIVATIVES; COUPLING REACTIONS; CONJUGATED ENYNES; HIGH-PERFORMANCE; LINEAR ACENES;

D O I：

10.1016/j.tet.2009.09.061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The CuX2-mediated reaction of enynal units, including ortho-alkynylbenzaldehydes, with alkynes gives a variety of haloaromatic compounds stereoselectively in good to high yields. 2,2'-Binaphthyl skeletons are also readily prepared by the reaction of ortho-alkynylbenzaldehydes and diynes. The method was applied to the synthesis of poly-substituted tetracene derivatives (C) 2009 Elsevier Ltd. All rights reserved

引用

页码：9575 / 9582

页数：8

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