Synthesis and studies on photochromic properties of vanadium doped TiO2 nanoparticles

被引：52

作者：

Songara, S. ^{[1
]}

Patra, M. K. ^{[1
]}

Manoth, M. ^{[1
]}

Saini, L. ^{[1
]}

Gupta, V. ^{[1
]}

Gowd, G. S. ^{[1
]}

Vadera, S. R. ^{[1
]}

Kumar, N. ^{[1
]}

机构：

[1] Def Lab, Jodhpur 342011, Rajasthan, India

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2010年 / 209卷 / 01期

关键词：

Vanadium doped nano-TiO2; Wet chemical method; Photochromism; THIN-FILMS; PHOTOCATALYTIC ACTIVITY; PHOTOREACTIVITY; OXIDES;

D O I：

10.1016/j.jphotochem.2009.11.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pure and (0.5-3 at%) vanadium doped TiO2 nanoparticles have been synthesized by wet chemical method. The as synthesized materials have been characterized by using XRD, atomic force microscope (AFM), Raman, EPR and UV-vis spectroscopy techniques. From XRD studies, both pure as well as vanadium doped TiO2 have been found to show Pure anatase phase. The value of lattice constant c is smaller in doped TiO2 as compared to undoped and has been found to decrease with increase in vanadium concentration. AFM Studies show formation of spherical particles with particle size similar to 23 nm in all the samples. Photochromic behavior of these materials has been Studied by making their films in alkyd resin. Vanadium doped TiO2 films show reversible change in color from beige-yellow to brownish violet on exposure to UV light. The mechanism of coloration and bleaching process has been discussed. (C) 2009 Elsevier B.V. All rights reserved

引用

页码：68 / 73

页数：6

共 38 条

[1] [Anonymous], METAL SEMICONDUCTORS
[2] [Anonymous], 1971, PHOTOCHROMISM TECHNI
[3] PHOTOELECTROCHEMISTRY
BARD, AJ
[J]. SCIENCE, 1980, 207 (4427) : 139 - 144
[4] Comparison between electrochromic and photochromic coloration efficiency of tungsten oxide thin films
Bechinger, C
Burdis, MS
Zhang, JG
[J]. SOLID STATE COMMUNICATIONS, 1997, 101 (10) : 753 - 756
[5] Role of nanoparticles in photocatalysis
Beydoun, D.
Amal, R.
Low, G.
McEvoy, S.
[J]. JOURNAL OF NANOPARTICLE RESEARCH, 1999, 1 (04) : 439 - 458
[6] Photoinduced reactivity of titanium dioxide
Carp, O
Huisman, CL
Reller, A
[J]. PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) : 33 - 177
[7] Investigation of transition metal ion doping behaviors on TiO2 nanoparticles
Chen, Jianhua
Yao, Maosheng
Wang, Xiaolin
[J]. JOURNAL OF NANOPARTICLE RESEARCH, 2008, 10 (01) : 163 - 171
[8] Preparation and photochromic behavior of crosslinked polymer thin films containing polyoxometalates
Chen, Jie
Liu, Yan
Xiong, De-Qi
Feng, Wei
Cai, Wei-Min
[J]. THIN SOLID FILMS, 2008, 516 (10) : 2864 - 2868
[9] Chen ZH, 2000, LANGMUIR, V16, P722, DOI 10.1021/1a9904197
[10] THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS
CHOI, WY
TERMIN, A
HOFFMANN, MR
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) : 13669 - 13679

← 1 2 3 4 →