Self-assembly and self-metallization of porphyrin nanosheets

被引:160
作者
Wang, Zhongchun
Li, Zhiyong
Medforth, Craig J.
Shelnutt, John A.
机构
[1] Sandia Natl Labs, Nanostruct & Semicond Phys Dept, Albuquerque, NM 87185 USA
[2] Hewlett Packard Labs, Palo Alto, CA 94304 USA
[3] Univ Georgia, Dept Chem, Athens, GA 30602 USA
关键词
D O I
10.1021/ja068250o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Square porphyrin nanosheets with uniform thickness (7-12 nm) and aspect ratios up to 100 have been synthesized for the first time using a reprecipitation method. They retain the photocatalytic activity of the precursor molecules and can be self-metallized with Pt, Pd, and Au. Their unique morphology, photocatalytic properties, and large surface areas suggest potential applications in photo- and electrocatalysis, sensing, as components for optoelectronic nanodevices, and solar energy capture and conversion.
引用
收藏
页码:2440 / +
页数:3
相关论文
共 21 条
  • [11] Molecular optical gating devices based on polymer nanosheets assemblies
    Matsui, J
    Mitsuishi, M
    Aoki, A
    Miyashita, T
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (12) : 3708 - 3709
  • [12] Micellization of block copolymers
    Riess, G
    [J]. PROGRESS IN POLYMER SCIENCE, 2003, 28 (07) : 1107 - 1170
  • [13] Macromolecule-like aspects for a colloidal suspension of an exfoliated titanate. Pairwise association of nanosheets and dynamic reassembling process initiated from it
    Sasaki, T
    Watanabe, M
    Hashizume, H
    Yamada, H
    Nakazawa, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (35) : 8329 - 8335
  • [14] Switchable electronic coupling in model oligoporphyrin molecular wires examined through the measurement and assignment of electronic absorption spectra
    Sendt, K
    Johnston, LA
    Hough, WA
    Crossley, MJ
    Hush, NS
    Reimers, JR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (31) : 9299 - 9309
  • [15] Controlled synthesis of 2-D and 3-D dendritic platinum nanostructures
    Song, YJ
    Yang, Y
    Medforth, CJ
    Pereira, E
    Singh, AK
    Xu, HF
    Jiang, YB
    Brinker, CJ
    van Swol, F
    Shelnutt, JA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) : 635 - 645
  • [16] Spreading behavior of short-branched N-alkylacrylamide polymers and the formation of Langmuir-Blodgett films
    Taniguchi, T
    Yokoyama, Y
    Miyashita, T
    [J]. MACROMOLECULES, 1997, 30 (12) : 3646 - 3649
  • [17] Fully conjugated porphyrin tapes with electronic absorption bands that reach into infrared
    Tsuda, A
    Osuka, A
    [J]. SCIENCE, 2001, 293 (5527) : 79 - 82
  • [18] Porphyrin nanotubes by ionic self-assembly
    Wang, ZC
    Medforth, CJ
    Shelnutt, JA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (49) : 15954 - 15955
  • [19] Self-metallization of photocatalytic porphyrin nanotubes
    Wang, ZC
    Medforth, CJ
    Shelnutt, JA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (51) : 16720 - 16721
  • [20] Porphyrin Nanofiber Bundles from Phase-Transfer Ionic Self-Assembly and Their Photocatalytic Self-Metallization
    Wang, Zhongchun
    Ho, Kuangchiu J.
    Medforth, Craig J.
    Shelnutt, John A.
    [J]. ADVANCED MATERIALS, 2006, 18 (19) : 2557 - +