Porous Metal-organic Framework based on Strip-shaped Manganese(II) Chains: Synthesis, Structure, and Magnetic Properties

被引：4
作者：
Liu, Jian-Jun [1 ]
He, Chi-Xian [1 ]
Cheng, Fei-Xiang [1 ]
Huang, Chang-Cang [2 ]
机构：
[1] Qujing Normal Univ, Ctr Yunnan Guizhou Plateau Chem Funct Mat & Pollu, Qujing 655011, Yunnan, Peoples R China
[2] Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 08期
基金：
中国国家自然科学基金;
关键词：
MOFs; Pentacluster; Manganese; Strip-shaped chain; Benzotriazole-5-carboxylate acid; Magnetic properties; NANOPOROUS COORDINATION FRAMEWORK; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; HELICAL CHAINS; CLUSTERS; TRANSFORMATION; SORPTION; POLYMER; PHOTOLUMINESCENT; ADSORPTION;
D O I：
10.1002/zaac.201700032
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Mn-II-based porous metal-organic framework, [Mn-3(btca)(2)(HCOO)((3)-OH)(H2O)(2)]2DMF (1) (H(2)btca = benzotriazole-5-carboxylate acid), was prepared by the solvothermal reaction of Mn(CH3COO)(2)4H(2)O and H(2)btca, which was characterized by infrared spectroscopy, thermogravimetric analyses, and X-ray crystallographic study. 1 exhibits 3D framework with 1D rectangle channels constructed by the strip-shaped chains containing [Mn-5((3)-OH)(2)(btca)(4)](-) pentaclusters subunits. Furthermore, the magnetic measures show that 1 exhibits weak ferromagnetic behavior at low temperature.
引用
收藏
页码：548 / 552
页数：5
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