A series of ruthenium(II) ester-carbene complexes as olefin metathesis initiators: metathesis of acrylates

被引：66
作者：
Ulman, M [1 ]
Belderrain, TR [1 ]
Grubbs, RH [1 ]
机构：
[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synthesis, Div Chem & Chem Engn, Pasadena, CA 91125 USA
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 24期
关键词：
olefin metathesis; catalyst; ruthenium; carbene; acrylate; ring-opening;
D O I：
10.1016/S0040-4039(00)00696-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of ester-carbene complexes was synthesized. These complexes were found to be highly active for the metathesis of olefinic substrates, including acrylates and trisubstituted olefins. In addition, the ester-carbene moiety is thermodynamically high in energy. As a result, these complexes react to ring-open cyclohexene by metathesis to alleviate the thermodynamic strain of the ester-carbene ligand. (C) 2000 Published by Elsevier Science Ltd.
引用
收藏
页码：4689 / 4693
页数：5
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