Pinacol coupling of aromatic aldehydes catalysed by a titanocene complex: A transition metal catalysed radical reaction

被引：136

作者：

Gansauer, A

机构：

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 05期

关键词：

D O I：

10.1039/a608438i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trinuclear complex derived from titanocene chloride and magnesium bromide is an efficient catalyst for the pinacol coupling of aromatic aldehydes; the 1,2-diols are obtained with good diastereoselectivity and a wide variety of sensitive functional groups are tolerated.

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页码：457 / 458

页数：2

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