In Situ Raman Monitoring of Silver(I)-Aided Laser-Driven Cleavage Reaction of Cyclobutane

被引：5

作者：

Chen, Dengtai ^{[1
]}

Han, Xijiang ^{[1
]}

Du, Yunchen ^{[1
]}

Wang, Hsing-Lin ^{[2
]}

Xu, Ping ^{[1
]}

机构：

[1] Harbin Inst Technol, Dept Chem, Harbin 150001, Peoples R China

[2] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

CHEMPHYSCHEM | 2016年 / 17卷 / 01期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

cleavage reactions; cyclobutane; laser chemistry; photochemistry; Raman spectroscopy; 2+2 CYCLOADDITION REACTION; REVERSIBLE SINGLE-CRYSTAL; SOLID-STATE; MAGNESIUM ACETATE; THERMAL CLEAVAGE; PLASMON-DRIVEN; PHOTODIMERIZATION; ISOMERIZATION; SPECTROSCOPY; REVEALS;

D O I：

10.1002/cphc.201500874

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cyclobutane cleavage reaction is an important process and has received continuous interest. Herein, we demonstrate the visible laser-driven cleavage reaction of cyclobutane in crystal form by using insitu Raman spectroscopy. Silver(I) coordination-induced strain and thermal effects from the laser irradiation are the two main driving forces for the cleavage of cyclobutane crystals. This work may open up a new avenue for studying cyclobutane cleavage reactions, as compared to the conventional routes using exsitu techniques.

引用

页码：46 / 50

页数：5

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