Removal of trimethylamine by adsorption over zeolite catalysts and deodorization of fish oil

Trimethylamine (TMA) is the main agent for the odor often associated with fouling fish, some infections, and bad breath. This study focused on the adsorption of TMA over various microporous zeolites for application in the low-temperature deodorization of fishy odor from raw fish oil. The faujasite (Si/Al = 3) zeolite exhibited the high adsorption ability, which, in combination with its wide surface area and pore volume, may have induced the high adsorption ability. The H-mordenite (Si/Al = 10) zeolite exhibited a large TMA adsorption. It was considered to have generated more attractive adsorption with TMA ions, because TMA interacted briskly with cations of acid sites on the zeolites. The fishy odor of raw fish oil was considerably reduced by low-temperature adsorption on the zeolites. The surface area of the zeolites retained most of the TMA adsorption ability, and their acid strength further enhanced the adsorption ability. (C) 2009 Elsevier B.V. All rights reserved.