μ-1,4-diazabicyclo[2.2.2]octane-κ2N:N′-bis[bis-(O,O′-diisopropyl dithiophosphato-κ2S,S′)zinc(II)]

被引：3

作者：

Ellis, Carol A.

Ng, Seik Weng

Tiekink, Edward R. T.

机构：

[1] Univ Texas, Dept Chem, San Antonio, TX 78249 USA

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536806052007

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The dinuclear title molecule, [Zn-2(C6H14O2PS2)(4)(C6H12N2)], is disposed about a centre of inversion and features a heavily distorted coordination geometry, owing to the presence of asymmetrically coordinating dithiophosphate ligands. In the crystal structure, molecules are stacked into layers, with connections between layers provided by C-H center dot center dot center dot O interactions.

引用

页码：M108 / M110

页数：3

共 12 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].