Fullerenes, zero-modes and self-adjoint extensions

We consider the low-energy electronic properties of graphene cones in the presence of a global Fries-Kekule Peierls distortion. Such cones occur in fullerenes as the geometric response to the disclination associated with pentagon rings. It is well known that the long-range effect of the disclination deficit-angle can be modelled in the continuum Dirac-equation approximation by a spin connection and a non-Abelian gauge field. We show here that to understand the bound states localized in the vicinity of a pair of pentagons one must, in addition to the long-range topological effects of the curvature and gauge flux, consider the effect of the short-range lattice disruption near the defect. In particular, the radial Dirac equation for the lowest angular-momentum channel sees the defect as a singular endpoint at the origin, and the resulting operator possesses deficiency indices (2, 2). The radial equation therefore admits a four-parameter set of self-adjoint boundary conditions. The values of the four parameters depend on how the pentagons are distributed and determine whether or not there are zero modes or other bound states.