Metal-organic coordination compounds for potential ferroelectrics

被引：198

作者：

Zhang, Wen ^{[1
]}

Ye, Heng-Yun ^{[1
]}

Xiong, Ren-Gen ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 23-24期

基金：

中国国家自然科学基金;

关键词：

Ferroelectricity; Polarization; Polar point groups; Metal-organic coordination compounds; Crystal structure; Homochirality; Hydrothemnal reaction; 2ND-HARMONIC GENERATION; FRAMEWORK; CRYSTAL; POLYMER; PERMITTIVITY; QUININE; HYBRID; ORDER; SHG;

D O I：

10.1016/j.ccr.2009.02.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A summary of recent work is p resented describing the synthesis and characterization of noncentrosymmetric or homochiral metal-organic coordination compounds (MOCCs) or metal-organic coordination polymers (MOCPs) which belong to 10 polar point groups with potential ferroelectric properties. Under the guidance of structure-function relationship, by using homochiral organic ligands as building blocks or supramolecular crystal engineering strategies, a series of potential ferroelectric MOCCs (or MOCPs) has been assembled through coordinating bond formation. Their ferroelectric behavior is measured and evaluated. Also the future development of ferroelectrics based on MOCCs is outlined. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：2980 / 2997

页数：18

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