Lead-Free Perovskite Materials for Solar Cells

被引:293
作者
Wang, Minghao [1 ,2 ]
Wang, Wei [1 ,2 ]
Ma, Ben [1 ,2 ]
Shen, Wei [1 ,2 ]
Liu, Lihui [1 ,2 ]
Cao, Kun [1 ,2 ]
Chen, Shufen [1 ,2 ,3 ,4 ]
Huang, Wei [1 ,2 ,3 ,4 ]
机构
[1] Nanjing Univ Posts & Telecommun NUPT, Key Lab Organ Elect & Informat Displays, Inst Adv Mat, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, 9 Wenyuan Rd, Nanjing 210023, Peoples R China
[2] Nanjing Univ Posts & Telecommun NUPT, Jiangsu Key Lab Biosensors, Inst Adv Mat, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, 9 Wenyuan Rd, Nanjing 210023, Peoples R China
[3] Northwestern Polytech Univ, Frontiers Sci Ctr Flexible Elect, Xian Inst Flexible Elect IFE, 127 West Youyi Rd, Xian 710072, Peoples R China
[4] Northwestern Polytech Univ, Xian Inst Biomed Mat & Engn, 127 West Youyi Rd, Xian 710072, Peoples R China
基金
中国国家自然科学基金;
关键词
Solar cells; Perovskite; Lead-free; First-principles calculation; Photovoltaic;
D O I
10.1007/s40820-020-00578-z
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
HighlightsThe toxicity issue of lead-based halide perovskites hinders theirs large-scale commercial applications in solar cells.A variety of non- or low-toxic perovskite materials have been used for development of environmentally friendly lead-free perovskite solar cells, some of which show excellent optoelectronic properties and device performances.At present, more new lead-free perovskite materials with tunable optical and electrical properties are urgently required to design highly efficient and stable lead-free perovskite solar cells. AbstractThe toxicity issue of lead hinders large-scale commercial production and photovoltaic field application of lead halide perovskites. Some novel non- or low-toxic perovskite materials have been explored for development of environmentally friendly lead-free perovskite solar cells (PSCs). This review studies the substitution of equivalent/heterovalent metals for Pb based on first-principles calculation, summarizes the theoretical basis of lead-free perovskites, and screens out some promising lead-free candidates with suitable bandgap, optical, and electrical properties. Then, it reports notable achievements for the experimental studies of lead-free perovskites to date, including the crystal structure and material bandgap for all of lead-free materials and photovoltaic performance and stability for corresponding devices. The review finally discusses challenges facing the successful development and commercialization of lead-free PSCs and predicts the prospect of lead-free PSCs in the future.
引用
收藏
页数:36
相关论文
共 194 条
[1]  
Abate A, 2017, JOULE, V1, P659, DOI 10.1016/j.joule.2017.09.007
[2]   Optoelectronic and photovoltaic properties of the air-stable organohalide semiconductor (CH3NH3)3Bi2I9 [J].
Abulikemu, Mutalifu ;
Ould-Chikh, Samy ;
Miao, Xiaohe ;
Alarousu, Erkki ;
Murali, Banavoth ;
Ndjawa, Guy Olivier Ngongang ;
Barbe, Jeremy ;
El Labban, Abdulrahman ;
Amassiana, Aram ;
Del Gobbo, Silvano .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (32) :12504-12515
[3]   Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide [J].
Ahn, Namyoung ;
Son, Dae-Yong ;
Jang, In-Hyuk ;
Kang, Seong Min ;
Choi, Mansoo ;
Park, Nam-Gyu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (27) :8696-8699
[4]   Influence of the composition of hybrid perovskites on their performance in solar cells [J].
Albero, Josep ;
Asiri, Abdullah M. ;
Garcia, Hermenegildo .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (12) :4353-4364
[5]   Lead-free, air-stable ultrathin Cs3Bi2I9 perovskite nanosheets for solar cells [J].
Bai, Fan ;
Hu, Yonghong ;
Hu, Yanqiang ;
Qiu, Ting ;
Miao, Xiaoliang ;
Zhang, Shufang .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2018, 184 :15-21
[6]   Lead-free perovskite solar cells using Sb and Bi-based A3B2X9 and A3BX6 crystals with normal and inverse cell structures [J].
Baranwal, Ajay Kumar ;
Masutani, Hideaki ;
Sugita, Hidetaka ;
Kanda, Hiroyuki ;
Kanaya, Shusaku ;
Shibayama, Naoyuki ;
Sanehira, Yoshitaka ;
Ikegami, Masashi ;
Numata, Youhei ;
Yamada, Kouji ;
Miyasaka, Tsutomu ;
Umeyama, Tomokazu ;
Imahori, Hiroshi ;
Ito, Seigo .
NANO CONVERGENCE, 2017, 4
[7]   Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells [J].
Bi, Cheng ;
Wang, Qi ;
Shao, Yuchuan ;
Yuan, Yongbo ;
Xiao, Zhengguo ;
Huang, Jinsong .
NATURE COMMUNICATIONS, 2015, 6
[8]   Efficient luminescent solar cells based on tailored mixed-cation perovskites [J].
Bi, Dongqin ;
Tress, Wolfgang ;
Dar, M. Ibrahim ;
Gao, Peng ;
Luo, Jingshan ;
Renevier, Clementine ;
Schenk, Kurt ;
Abate, Antonio ;
Giordano, Fabrizio ;
Baena, Juan-Pablo Correa ;
Decoppet, Jean-David ;
Zakeeruddin, Shaik Mohammed ;
Nazeeruddin, Mohammad Khaja ;
Gratzel, Michael ;
Hagfeldt, Anders .
SCIENCE ADVANCES, 2016, 2 (01)
[9]   Thermally Induced Bi(III) Lone Pair Stereoactivity: Ferroelectric Phase Transition and Semiconducting Properties of (MV)BiBr5 (MV = methylviologen) [J].
Bi, Wenhua ;
Leblanc, Nicolas ;
Mercier, Nicolas ;
Auban-Senzier, Pascale ;
Pasquier, Claude .
CHEMISTRY OF MATERIALS, 2009, 21 (18) :4099-4101
[10]  
Brenner TM, 2016, NAT REV MATER, V1, DOI 10.1038/natrevmats.2015.7