Isocyanide Insertion-Cyclization Reaction for Imidazoisoindol-5-imine Scaffold Synthesis: A Selective Solvatochromic Fluorescent Probe for Methanol Detection

被引：10

作者：

Ahmadi, Fereshteh ^{[1
,2
]}

Goli, Hamid Reza ^{[1
]}

Balmohammadi, Yaser ^{[1
]}

Bazgir, Ayoob ^{[1
]}

机构：

[1] Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran

[2] KN Toosi Univ Technol, Fac Chem, Dept Organ Chem, Tehran 15418, Iran

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 86卷 / 01期

基金：

美国国家科学基金会;

关键词：

DENSITY-FUNCTIONAL THERMOCHEMISTRY; SENSOR; NANOPARTICLES;

D O I：

10.1021/acs.joc.0c01860

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient, ligand-free, and Pd-catalyzed method for the synthesis of imidazoisoindole imine scaffolds with satisfactory yields via C-C and C-N bond formation has been developed. The synthesized scaffolds have unique potential for selective MeOH detection from other solvents, especially EtOH. The appealing features of this transformation are phosphinic ligand-free conditions, the use of a small amount of Pd(OAc)(2), and a practical procedure for the synthesis of imidazoisoindole imine scaffolds.

引用

收藏

页码：146 / 152

页数：7

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