2-Nitrobenzaldehyde as a chemical actinometer for solution and ice photochemistry

2-Nitrobenzaldehyde (2NB) is a convenient, photochemically sensitive, and thermally robust actinometer. Although 2NB has been used in a number of solution and ice experiments in the laboratory, the quantum efficiencies and molar absorptivities of 2NB have not been critically evaluated, especially on ice. Using a series of laboratory and field measurements we have measured the light absorbance and photochemical properties of 2-nitrobenzaldehyde in solution (water and/or acetonitrile) and in/on water ice. Our results show that the molar absorptivities of 2NB are only weakly dependent upon temperature and that the quantum yield is independent of temperature in water; the quantum yield is also independent of wavelength, as shown by past reports. Furthermore, we find that the photochemistry of 2NB in/on water ice is the same as in liquid water. While most studies employing 2NB cite and use a quantum yield of 0.50, based on a review of the literature, and on our new experimental data, we recommend a quantum yield of 0.41 for 2NB photolysis for both solution and water ice. (C) 2009 Elsevier B.V. All rights reserved.