Synthesis, structure and characterization of binuclear copper(I) complexes

被引：38

作者：

Yang, RN ^{[1
]}

Lin, KH ^{[1
]}

Hou, KM ^{[1
]}

Wang, DM ^{[1
]}

Jin, DM ^{[1
]}

Luo, BS ^{[1
]}

Chen, LR ^{[1
]}

机构：

[1] WUHAN UNIV,DEPT CHEM,WUHAN 470053,PEOPLES R CHINA

来源：

TRANSITION METAL CHEMISTRY | 1997年 / 22卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1023/A:1018412524042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Binuclear copper(I) complexes [Cu(dppm)(NO3)](2) (1), dppm = Ph2PCH2PPh2, [Cu(dppm)(2,9-Me(2)Phen)](2)(NO3)(2) (2), [Cu(dppm)(I)](2) (3) and [Cu(dppm)(py)](2)(NO3)(2) (4), (py = pyridine) have been synthesized by ligand reduction of cupric nitrate with dppm in EtOH and characterized by elemental analyses, molecular weight determination, t.g.a., P-31-n.m.r spectra, their electronic conductivities and c.v. waves have also been measured. The results show that dppm coordinates as a bridging bidentate ligand to the Cu atoms, and that NO3 behaves as a monodentate ligand or free ion in the newly prepared complexes.

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页码：254 / 258

页数：5

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