Analysis of Raman modes in Mn-doped ZnO nanocrystals

被引:90
作者
Guo, Shuxia [1 ,2 ]
Du, Zuliang [2 ]
Da, Shuxi [2 ]
机构
[1] Jiaozuo Teachers Coll, Dept Phys, Jiaozuo 454001, Peoples R China
[2] Henan Univ, Minist Educ, Key Lab Special Funct Mat, Kaifeng 475004, Peoples R China
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2009年 / 246卷 / 10期
关键词
ROOM-TEMPERATURE; THIN-FILMS; SCATTERING; FERROMAGNETISM; BULK;
D O I
10.1002/pssb.200945192
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Mn-doped ZnO was synthesized using a co-precipitation technique. X-ray diffraction (XRD) measurements and photoluminescence (PL) spectra show that Mn ions are doped into the lattice positions of ZnO. The modes at 202, 330, and 437 cm(-1) in the Raman spectrum are assigned as 2E(2) (low), E-2 (high)-E-2 (low), and E-2 (high) modes of ZnO base, respectively. The mode at 528 cm(-1) is ascribed to a local vibrational mode related to Mn. The mode at 580 cm(-1) should be an intrinsic mode of ZnO and assigned to E-1 longitudinal optical (LO). Its reinforcement should result from a combination of resonance at the excitation wavelength and impurity-induced scattering. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:2329 / 2332
页数:4
相关论文
共 20 条
[1]   Micro-Raman investigation of optical phonons in ZnO nanocrystals [J].
Alim, KA ;
Fonoberov, VA ;
Shamsa, M ;
Balandin, AA .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (12)
[2]   Raman scattering of polar modes of ZnO crystallites [J].
Bergman, L ;
Chen, XB ;
Huso, J ;
Morrison, JL ;
Hoeck, H .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (09)
[3]   Raman scattering in ZnO thin films doped with Fe, Sb, Al, Ga, and Li [J].
Bundesmann, C ;
Ashkenov, N ;
Schubert, M ;
Spemann, D ;
Butz, T ;
Kaidashev, EM ;
Lorenz, M ;
Grundmann, M .
APPLIED PHYSICS LETTERS, 2003, 83 (10) :1974-1976
[4]   RESONANT RAMAN-SCATTERING IN ZNO [J].
CALLEJA, JM ;
CARDONA, M .
PHYSICAL REVIEW B, 1977, 16 (08) :3753-3761
[5]   Production and recovery of defects in phosphorus-implanted ZnO [J].
Chen, ZQ ;
Kawasuso, A ;
Xu, Y ;
Naramoto, H ;
Yuan, XL ;
Sekiguchi, T ;
Suzuki, R ;
Ohdaira, T .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (01)
[6]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[7]   Structure and magnetism in the Zn-Mn-O system:: A candidate for room temperature ferromagnetic semiconductor [J].
Fernandez, J. F. ;
Caballero, A. C. ;
Villegas, M. ;
Khatib, S. J. ;
Banares, M. A. ;
Fierro, J. L. G. ;
Costa-Kramer, J. L. ;
Lopez-Ponce, E. ;
Martin-Gonzalez, M. S. ;
Briones, F. ;
Quesada, A. ;
Garcia, M. ;
Hernando, A. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (14) :3017-3025
[8]   Interface and confined optical phonons in wurtzite nanocrystals [J].
Fonoberov, VA ;
Balandin, AA .
PHYSICAL REVIEW B, 2004, 70 (23) :1-4
[9]   Raman scattering study of ZnO:Ti and ZnO:Mn bulk crystals [J].
Gebicki, W ;
Osuch, K ;
Jastrzebski, C ;
Golacki, Z ;
Godlewski, M .
SUPERLATTICES AND MICROSTRUCTURES, 2005, 38 (4-6) :428-438
[10]   Impurity-induced resonance Raman scattering at the (e, A0) threshold in lightly carbon-doped p-type GaAs at 2 K [J].
Huang, Q ;
Ulbrich, RG .
JOURNAL OF LUMINESCENCE, 2002, 99 (01) :19-28