Melt Flow Instabilities of Wood Polymer Composites

被引:9
作者
Hristov, Velichko [1 ]
机构
[1] Borealis Polyolefine GmbH, R&D Compound Res, A-4021 Linz, Austria
关键词
Wood fiber composites; flow instabilities; rheology; surface tearing; melt fracture; LOW-DENSITY POLYETHYLENE; ENTRANCE PRESSURE LOSS; WALL SLIP; CONCENTRATED SUSPENSIONS; EXTRUSION INSTABILITIES; RHEOLOGICAL PROPERTIES; EXTRUDATE DISTORTIONS; MECHANICAL-PROPERTIES; APPARENT SLIP; BEHAVIOR;
D O I
10.1163/092764409X12477434799525
中图分类号
TB33 [复合材料];
学科分类号
摘要
Melt flow instabilities during extrusion of wood polymer composites (WPC) containing 30-60 wt% wood flour (WF) have been investigated. The research emphasized elucidation of the extrudate surface tearing mechanism and its relation to wall slip. This interesting phenomenon has been known in the WPC industry for years; however, it has not received much research interest. It was observed that increasing the wood flour loading up to 50 wt% aggravated the surface tearing; however, addition of 60 wt% wood flour completely eliminated the surface defect due to strong wall slip and plug flow. It was also found that addition Of lubricants and increasing the shear rate significantly improved the Surface appearance of the filled compounds. Molecular weight and molecular weight distribution of the polymer matrix influence the melt flow properties of the composites. The significance of the entrance pressure measurement and its usefulness for quantitative assessment of filler-matrix interactions in composite materials is also demonstrated in this paper. (C) Koninklijke Brill NV, Leiden, 2009
引用
收藏
页码:731 / 750
页数:20
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