Experimental study of phase equilibria in the PbO-ZnO-"Fe2O3"-CaO-SiO2 system in air for high lead smelting slags (CaO/SiO2=0.35 and PbO/(CaO+SiO2)=5.0 by weight)

被引：26
作者：
Jak, E [1 ]
Hayes, PC [1 ]
机构：
[1] Univ Queensland, Sch Engn, Pyromet Res Ctr, PYROSEARCH, St Lucia, Qld 4072, Australia
来源：
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE | 2002年 / 33卷 / 06期
基金：
澳大利亚研究理事会;
关键词：
Material Transaction; Zinc Ferrite; Slag System; Zincite; Dicalcium Silicate;
D O I：
10.1007/s11663-002-0065-7
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Experimental studies on phase equilibria in the multicomponent system PbO-ZnO-CaO-SiO2-FeO-Fe2O3 in air have been conducted to characterize the phase relations of a complex slag system used in commercial lead oxidation smelting. The liquidus in the pseudo-ternary section ZnO-"Fe2O3"-(PbO + CaO + SiO2) with the CaO/SiO2 weight ratio of 0.35 and the PbO/(CaO + SiO2) weight ratio of 5.0 has been constructed using results of over 100 high-temperature equilibration and quenching experiments followed by electron probe X-ray microanalysis. The liquidus in this pseudoternary section contains primary phase fields of spinel (zinc ferrite) ZnxFe3-xO4+y, zincite ZnuFe1-uO, melilite PbvCa2-vZnwFe1-wSi2O7, hematite Fe2O3, magneto-plumbite PbFe10O16, and dicalcium silicate Ca2-t PbtSiO4. The laboratory results are compared with the slags obtained from an industrial reactor.
引用
收藏
页码：817 / 825
页数：9
相关论文
共 12 条
[1]  
ERRINGTON WJ, 1985, EXTRACTION METALLURG, P199
[2]   Experimental liquidus in the PbO-ZnO-"Fe2O3"-(CaO+SiO2) system in air, with CaO/SiO2=0.35 and PbO/(CaO+SiO2)=3.2 [J].
Jak, E ;
Hayes, PC .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2002, 33 (06) :851-863
[3]   Experimental study of phase equilibria in the systems PbOx-CaO and PbOx-CaO-SiO2 [J].
Jak, E ;
Liu, NG ;
Hayes, PC .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 1998, 29 (03) :541-553
[4]   Experimental study of phase equilibria in the systems Fe-Zn-O and Fe-Zn-Si-O at metallic iron saturation [J].
Jak, E ;
Zhao, B ;
Hayes, PC .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2000, 31 (06) :1195-1201
[5]   Experimental study of phase equilibria in the system PbO-ZnO-SiO2 [J].
Jak, E ;
Zhao, BJ ;
Liu, NG ;
Hayes, PC .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 1999, 30 (01) :21-27
[6]   Coupled experimental and thermodynamic modeling studies for metallurgical smelting and coal combustion slag systems [J].
Jak, E ;
Degterov, S ;
Zhao, B ;
Pelton, AD ;
Hayes, PC .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2000, 31 (04) :621-630
[7]  
JAK E, 1995, P LEAD ZINC 95 INT S, P747
[8]  
Jak E., 1994, 6 AUSIMM EXTRACTIVE, P253
[9]  
JAK E, 1994, P 6 AUSIMM EXTR MET, P261
[10]  
Jak E., 1995, KOREAN IMM J, V1, P1, DOI DOI 10.1007/BF03055319
12