Blue, green, red and near-infrared emissions via upconversion in α-sialon

被引:10
作者
Kshetri, Yuwaraj K. [1 ]
Joshi, Bhupendra [2 ]
Kim, Tae-Ho [2 ]
Lee, Soo Wohn [2 ]
机构
[1] Sun Moon Univ, Dept Adv Mat Engn, Chungnam 31460, South Korea
[2] Sun Moon Univ, Dept Environm & Biochem Engn, Chungnam 31460, Peoples R China
基金
新加坡国家研究基金会;
关键词
alpha-Sialon; Hot pressing; Energy transfer; Upconversion; WHITE-LIGHT; CERAMICS; NANOCRYSTALS; LUMINESCENCE; LANTHANIDE;
D O I
10.1016/j.matlet.2017.04.060
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Near-infrared to visible and near-infrared upconversion emission has been reported in Yb3+/Ln(3+) (Ln(3+) = Er3+/Tm3+/Ho3+)-alpha-sialon ceramic prepared by hot press sintering technique. Under 980 nm excitation, blue, green, red and near-infrared emissions are observed simultaneously as a result of the efficient energy transfer from Yb3+ to Er3+, Tm3+, and Ho3+ ions leading to a near-white light emission with CIE color coordinate of (0.38, 0.45). The two-and three-photon absorption processes are responsible for the observed upconversion emissions. The ceramic has moderately low phonon energy of 835 cm(-1). These novel properties make the material a promising candidate for upconversion applications. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:147 / 150
页数:4
相关论文
共 12 条
[1]  
AUZEL F, 1966, CR ACAD SCI B PHYS, V262, P1016
[2]  
Dieke GH., 1970, AM J PHYS, V38, P399, DOI DOI 10.1119/1.1976350
[3]   Vapor phase synthesis of upconverting Y2O3 nanocrystals doped with Yb3+, Er3+, Ho3+, and Tm3+ to generate red, green, blue, and white light [J].
Glaspell, Garry ;
Anderson, John ;
Wilkins, James R. ;
Ei-Shall, M. Samy .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (30) :11527-11531
[4]   ALPHA'-SIALON CERAMICS [J].
HAMPSHIRE, S ;
PARK, HK ;
THOMPSON, DP ;
JACK, KH .
NATURE, 1978, 274 (5674) :880-882
[5]   Efficient Near Infrared to Visible and Near-Infrared Upconversion Emissions in Transparent (Tm3+, Er3+)--Sialon Ceramics [J].
Kshetri, Yuwaraj K. ;
Joshi, Bhupendra ;
Armando Diaz-Torres, Luis ;
Lee, Soo Wohn .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2017, 100 (01) :224-234
[6]   Intense visible upconversion emission in transparent (Ho3+, Er3+)-α-Sialon ceramics under 980 nm laser excitation [J].
Kshetri, Yuwaraj K. ;
Joshi, Bhupendra ;
Lee, Soo Wohn .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2016, 36 (16) :4215-4224
[7]   Improvement of high temperature strength and creep of α-sialon by grain boundary crystallization [J].
Nishimura, T ;
Mitomo, M ;
Ishida, A ;
Gu, H .
CREEP AND FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, 2000, 171-1 :741-746
[8]   Controllable synthesis and up-conversion properties of tetragonal BaYF5:Yb/Ln (Ln = Er, Tm, and Ho) nanocrystals [J].
Niu, Na ;
Yang, Piaoping ;
Liu, Yanchao ;
Li, Chunxia ;
Wang, Dong ;
Gai, Shili ;
He, Fei .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 362 (02) :389-396
[9]   Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems [J].
Pollnau, M ;
Gamelin, DR ;
Lüthi, SR ;
Güdel, HU ;
Hehlen, MP .
PHYSICAL REVIEW B, 2000, 61 (05) :3337-3346
[10]   Multicolor and bright white upconversion luminescence from rice-shaped lanthanide doped BiPO4 submicron particles [J].
Wang, Zhuo ;
Feng, Jing ;
Pang, Min ;
Pan, Shunhao ;
Zhang, Hongjie .
DALTON TRANSACTIONS, 2013, 42 (34) :12101-12108