Syntheses and characterization of chloro(Me2SO)ruthenium(II) complexes with tris(2-pyridylmethyl)amine or N,N-bis(2-pyridylmethyl)glycinate and their application for catalytic hydroxylation of alkane

被引：39

作者：

Yamaguchi, M

Kousaka, H

Yamagishi, T

机构：

[1] Department of Industrial Chemistry, Graduate School of Engineering, Tokyo Metropolitan University, Minami-osawa

来源：

CHEMISTRY LETTERS | 1997年 / 08期

关键词：

D O I：

10.1246/cl.1997.769

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new ruthenium(II) complexes, [RuCl(Me2SO)(TPA)]X (X = Cl or PF6) and [Ru(BPG)Cl(Me2SO)] were prepared, and the catalytic activity for alkane hydroxylation using m-chloroperbenzoic acid was examined.(2) Two geometrical isomers of the TPA complexes were isolated and showed marked difference in activity: the trans(Cl, N-amino) isomer is the most active and selective catalyst toward the oxygenation of adamantane giving 1-adamantanol (75%) and 2-adamantanol (5%).

引用

页码：769 / 770

页数：2

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