Synthesis of 2-pentafluorosulfanylnaphthalene

被引：13

作者：

Dolbier, William R., Jr. ^{[1
]}

Mitani, Akira ^{[1
]}

Warren, Robin D. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 08期

基金：

美国国家科学基金会;

关键词：

SF5; group; pentafluorosulfanyl group; naphthalene; SF5Cl;

D O I：

10.1016/j.tetlet.2006.12.123

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A three step synthesis of 2-pentafluorosulfanylnaphthalene is reported. Initial addition of SF5Cl to benzobarralene was followed by elimination to form 2-pentafluorosulfanylbenzobarralene. Heating of this compound with 3,6-bis-(2-pyridyl)-1,2,4,5-tetrazine led to elimination of the ethylene bridge via a sequence of cycloadditions and retro-cycloadditions to form the title compound. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1325 / 1326

页数：2

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