Room temperature ozone sensing properties of p-type transparent oxide CuCrO2

被引:30
作者
Deng, Zanhong [1 ,2 ]
Fang, Xiaodong [1 ,2 ]
Li, Da [1 ,2 ]
Zhou, Shu [1 ,2 ]
Tao, Ruhua [1 ,2 ]
Dong, Weiwei [1 ,2 ]
Wang, Tao [1 ]
Meng, Gang [1 ]
Zhu, Xuebin [2 ,3 ]
机构
[1] Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
[2] Chinese Acad Sci, Key Lab Novel Thin Film Solar Cells, Hefei 230031, Peoples R China
[3] Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Peoples R China
关键词
Semiconductors; Oxide materials; Electronic properties; Optical properties; PULSED-LASER DEPOSITION; THIN-FILMS; CUALO2;
D O I
10.1016/j.jallcom.2009.05.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The sintered bulk CuCrO2 and thin film were prepared by sol-gel and pulsed laser deposition, respectively. They show rhombohedral 3R structure, wide band gap and p-type semiconducting properties. These properties are similar with those of CuAlO2, which has been found to be a promising candidate for inexpensive p-type and transparent ozone sensor. In this study, the room temperature ozone sensing properties of the sintered bulk CuCrO2 and thin film were investigated. Furthermore, transparent p-type semiconductor CuCrO2 shows selective and reversible response to ozone at room temperature. This study suggests that CuCrO2 can be another promising candidate for parent materials of room temperature ozone sensor besides CuAlO2. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:619 / 621
页数:3
相关论文
共 14 条
[1]   Recent advances in optochemical sensors for the detection of H2, O2, O3, CO, CO2 and H2O in air [J].
Ando, Masanori .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2006, 25 (10) :937-948
[2]   Production and characterization of zinc oxide thin films for room temperature ozone sensing [J].
Bender, M ;
Gagaoudakis, E ;
Douloufakis, E ;
Natsakou, E ;
Katsarakis, N ;
Cimalla, V ;
Kiriakidis, G ;
Fortunato, E ;
Nunes, P ;
Marques, A ;
Martins, R .
THIN SOLID FILMS, 2002, 418 (01) :45-50
[3]   The influence of growth temperature and oxygen on the phase compositions of CuAlO2 thin films prepared by pulsed laser deposition [J].
Deng, Zanhong ;
Fang, Xiaodong ;
Tao, Ruhua ;
Dong, Weiwei ;
Li, Da ;
Zhu, Xuebin .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 466 (1-2) :408-411
[4]   Synthesis of CuAlO2 ceramics using sol-gel [J].
Deng, Zanhong ;
Zhu, Xuebin ;
Tao, Ruhua ;
Don, Weiwei ;
Fang, Xiaodong .
MATERIALS LETTERS, 2007, 61 (03) :686-689
[5]   The influence of deposition parameters on room temperature ozone sensing properties of InOx films [J].
Gagaoudakis, E ;
Bender, M ;
Douloufakis, E ;
Katsarakis, N ;
Natsakou, E ;
Cimalla, V ;
Kiriakidis, G .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 80 (02) :155-161
[6]   P-type electrical conduction in transparent thin films of CuAlO2 [J].
Kawazoe, H ;
Yasukawa, M ;
Hyodo, H ;
Kurita, M ;
Yanagi, H ;
Hosono, H .
NATURE, 1997, 389 (6654) :939-942
[7]   Ozone sensing properties of In2O3-based semiconductor thick films [J].
Kim, SR ;
Hong, HK ;
Kwon, CH ;
Yun, DH ;
Lee, K ;
Sung, YK .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 66 (1-3) :59-62
[8]   Electrical, optical and structural properties of CuCrO2 films prepared by pulsed laser deposition [J].
Li, Da ;
Fang, Xiaodong ;
Deng, Zanhong ;
Zhou, Shu ;
Tao, Ruhua ;
Dong, Weiwei ;
Wang, Tao ;
Zhao, Yiping ;
Meng, Gang ;
Zhu, Xuebin .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (16) :4910-4915
[9]   Magnetic and electrical properties of p-type Mn-doped CuCrO2 semiconductors [J].
Li, Da ;
Fang, Xiaodong ;
Dong, Weiwei ;
Deng, Zanhong ;
Tao, Ruhua ;
Zhou, Shu ;
Wang, Jinmei ;
Wang, Tao ;
Zhao, Yiping ;
Zhu, Xuebin .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (05)
[10]   Realizing the semiconducting state of delafossite AgFeO2 by GGA + U calculations [J].
Ong, Khuong P. ;
Bai, Kewu ;
Wu, Ping .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 449 (1-2) :366-370