Metal-organic frameworks as advanced sorbents in sample preparation for small organic analytes

被引：87

作者：

Li, Xianjiang ^{[1
]}

Ma, Wen ^{[2
]}

Li, Hongmei ^{[1
]}

Bai, Yu ^{[3
]}

Liu, Huwei ^{[3
]}

机构：

[1] Natl Inst Metrol, Div Metrol Chem, Food Safety Lab, Beijing 100029, Peoples R China

[2] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

[3] Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Inst Analyt Chem,Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2019年 / 397卷

基金：

中国国家自然科学基金;

关键词：

Sample preparation; Metal-organic frameworks; Solid-phase extraction; Small organic analytes; SOLID-PHASE EXTRACTION; POLYCYCLIC AROMATIC-HYDROCARBONS; BAR SORPTIVE EXTRACTION; PERFORMANCE LIQUID-CHROMATOGRAPHY; ZEOLITIC IMIDAZOLATE FRAMEWORK-8; POLYBROMINATED DIPHENYL ETHERS; ENVIRONMENTAL WATER SAMPLES; GAS-CHROMATOGRAPHY; MASS-SPECTROMETRY; POLYCHLORINATED-BIPHENYLS;

D O I：

10.1016/j.ccr.2019.06.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs) are a class of hybrid organic-inorganic materials with porous structure. With the merit of high surface area, uniform nanoscale cavity, good thermal and chemical stability and tailorable chemistry, this class of materials has recently attracted wide attention in sample preparation field. This review mainly focuses on various applications of MOFs as advanced sorbent materials in small organic analytes' enrichment, including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), volatile organic compounds (VOCs), pharmaceuticals, herbicides, pesticides, toxins, dyes, endocrine-disrupting chemicals (EDCs) and other compounds. Limitations of MOFs as sorbents are presented in detail, and further perspectives are discussed at last. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：1 / 13

页数：13

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