The UV/peroxymonosulfate process for the mineralization of artificial sweetener sucralose
被引:75
作者:
Xu, Yin
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Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
Wuhan Univ, Shenzhen Res Inst, Shenzhen 518057, Peoples R ChinaWuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
Xu, Yin
[1
,2
]
Lin, Ziyan
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机构:
Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R ChinaWuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
Lin, Ziyan
[1
]
Wang, Yan
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机构:
Anhui Sci & Technol Univ, Dept Environm Sci & Engn, Donghua Rd 9, Fengyang 233100, Peoples R ChinaWuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
Wang, Yan
[3
]
Zhang, Hui
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Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
Wuhan Univ, Shenzhen Res Inst, Shenzhen 518057, Peoples R ChinaWuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
Zhang, Hui
[1
,2
]
机构:
[1] Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China
[2] Wuhan Univ, Shenzhen Res Inst, Shenzhen 518057, Peoples R China
[3] Anhui Sci & Technol Univ, Dept Environm Sci & Engn, Donghua Rd 9, Fengyang 233100, Peoples R China
As one of non-nutritive and commonly used artificial sweeteners, sucralose (SUC) is now ubiquitous and detected in aquatic environments, which has already been recognized as an emerging contaminant. The mineralization of SUC in aqueous media by UV/peroxymonosulfate (PMS) process is investigated herein. Influences of several operating parameters, including pH, oxidant concentration and initial SUC concentration, on SUC mineralization were evaluated. Changing the pH from 3 to 9 had a weak effect on the mineralization of SUC, but the mineralization efficiency dropped sharply at pH 11. Nearly complete mineralization (> 95%) of SUC was achieved after 60 min treatment with 3.780 mM oxidant at neutral pH. Both hydroxyl and sulfate radicals were demonstrated to participate in the oxidation of SUC according to EPR analysis. Under neutral pH condition, the presence of inorganic anion such as Cl-, NO3- or NO2- exhibited a varied inhibition effect on the mineralization efficiency with the order being NO2- > NOT > Cl-. Activated sludge inhibition tests and Daphnia magna acute immobilization tests were performed to evaluate the detoxification efficiency of the UV/PMS process. The by-products formed were identified using LC-MS technique and a possible pathway of SUC degradation was proposed. In summary, the obtained result provides meaningful information on the application of UV/PMS process for the mineralization of SUC or other artificial sweeteners. (C) 2017 Elsevier B.V. All rights reserved.
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Deng, Jing
Shao, Yisheng
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
China Acad Urban Planning & Design, Beijing 100037, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Shao, Yisheng
Gao, Naiyun
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Gao, Naiyun
Xia, Shengji
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Xia, Shengji
Tan, Chaoqun
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Tan, Chaoqun
Zhou, Shiqing
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Zhou, Shiqing
Hu, Xuhao
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Deng, Jing
Shao, Yisheng
论文数: 0引用数: 0
h-index: 0
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
China Acad Urban Planning & Design, Beijing 100037, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Shao, Yisheng
Gao, Naiyun
论文数: 0引用数: 0
h-index: 0
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Gao, Naiyun
Xia, Shengji
论文数: 0引用数: 0
h-index: 0
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Xia, Shengji
Tan, Chaoqun
论文数: 0引用数: 0
h-index: 0
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Tan, Chaoqun
Zhou, Shiqing
论文数: 0引用数: 0
h-index: 0
机构:
Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China
Zhou, Shiqing
Hu, Xuhao
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Tongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R ChinaTongji Univ, State Key Lab Pollut Control Reuse, Shanghai 200092, Peoples R China