Ligand-free copper-catalyzed C(sp3)-H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide

被引：4

作者：

Wang, Si-Chang ^{[1
]}

Feng, Ming-Nan ^{[1
]}

Ji, Yue ^{[1
]}

Han, Wei-Wei ^{[1
]}

Ke, Cong-Yu ^{[1
]}

Zhang, Qun-Zheng ^{[1
]}

Zhang, Xun-Li ^{[1
]}

机构：

[1] Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Peoples R China

来源：

RSC ADVANCES | 2021年 / 11卷 / 20期

关键词：

C-H AMINATION; NITROGEN-SOURCE; METAL-FREE; AMIDATION; FLUORINATION; ALKYNES; BONDS; FLUOROARYLSULFONIMIDES; AMINOARYLATION; HETEROCYCLES;

D O I：

10.1039/d1ra00686j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel and efficient process has been developed for copper-catalyzed C(sp(3))-H direct imidation of methyl sulfides with N-fluorobenzenesulfonimide(NFSI). Without using any ligands, various methyl sulfides including aromatic and aliphatic methyl sulfides, can be transformed to the corresponding N-((phenylthio)methyl)-benzenesulfonamide derivatives in good to excellent yields.

引用

页码：12136 / 12140

页数：5

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