Synthesis of α-alkylidene cyclic carbonates via CO2 fixation under ambient conditions promoted by an easily available silver carbamate

被引：18
作者：
Bresciani, Giulio [1 ,2 ]
Bortoluzzi, Marco [2 ,3 ]
Ghelarducci, Claudia [1 ]
Marchetti, Fabio [1 ,2 ]
Pampaloni, Guido [1 ,2 ]
机构：
[1] Univ Pisa, Dipartimento Chim & Chim Ind, Via Moruzzi 13, I-56124 Pisa, Italy
[2] CIRCC, Via Celso Ulpiani 27, I-70126 Bari, Italy
[3] Ca Foscari Univ Venezia, Dipartimento Sci Mol & Nanosistemi, Via Torino 155, I-30170 Venice, VE, Italy
来源：
NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 09期
关键词：
COMPLEXES;
D O I：
10.1039/d0nj05657j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The simple and cost-effective compound [Ag(O2CNEt2)], in combination with PPh3, works as an effective catalytic precursor in the carboxylation of propargyl alcohols at ambient temperature and atmospheric CO2 pressure, and in most cases under solventless conditions. The silver carbamate revealed a better performance than commercial silver oxide, Ag2O, and allowed to obtain a series of alpha-alkylidene cyclic carbonates in high yields.
引用
收藏
页码：4340 / 4346
页数：7
相关论文
共 62 条
[1]  
AGOSTINELLI E, 1988, GAZZ CHIM ITAL, V118, P729
[2]   N,N-dialkylcarbamato complexes of the d10 cations of copper, silver, and gold [J].
Alessio, R ;
Dell'Amico, DB ;
Calderazzo, F ;
Englert, U ;
Guarini, A ;
Labella, L ;
Strasser, P .
HELVETICA CHIMICA ACTA, 1998, 81 (02) :219-230
[3]   ENERGY-ADJUSTED ABINITIO PSEUDOPOTENTIALS FOR THE 2ND AND 3RD ROW TRANSITION-ELEMENTS [J].
ANDRAE, D ;
HAUSSERMANN, U ;
DOLG, M ;
STOLL, H ;
PREUSS, H .
THEORETICA CHIMICA ACTA, 1990, 77 (02) :123-141
[4]  
[Anonymous], 2004, Essentials of computational chemistry
[5]   Israel Chemical Society Prizes [J].
Apeloig, Yitzhak ;
Shaik, Sason ;
Martin, Gershom ;
Meyerstein, Dan ;
Ruthstein, Sharon ;
van der Boom, Milko E. ;
Doudna, Jennifer A. ;
Mirkin, Chad A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (18) :4833-4834
[6]   Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment [J].
Artz, Jens ;
Mueller, Thomas E. ;
Thenert, Katharina ;
Kleinekorte, Johanna ;
Meys, Raoul ;
Sternberg, Andre ;
Bardow, Andre ;
Leitner, Walter .
CHEMICAL REVIEWS, 2018, 118 (02) :434-504
[7]   Quantum calculation of molecular energies and energy gradients in solution by a conductor solvent model [J].
Barone, V ;
Cossi, M .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (11) :1995-2001
[8]  
Belli D., 2000, INORG CHIM ACTA, V302, P882
[9]   Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates [J].
Biancalana, Lorenzo ;
Bresciani, Giulio ;
Chiappe, Cinzia ;
Marchetti, Fabio ;
Pampaloni, Guido ;
Pomelli, Christian Silvio .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (07) :5057-5066
[10]   Recent Advances in the Chemistry of Metal Carbamates [J].
Bresciani, Giulio ;
Biancalana, Lorenzo ;
Pampaloni, Guido ;
Marchetti, Fabio .
MOLECULES, 2020, 25 (16)
1234567