Recent Progress in Trivalent Actinide and Lanthanide Solvent Extraction and Coordination Chemistry with Triazinylpyridine N Donor Ligands

被引：42
作者：
Geist, Andreas [1 ]
Panak, Petra J. [1 ,2 ]
机构：
[1] Karlsruhe Inst Technol KIT, Inst Nucl Waste Disposal INE, Karlsruhe, Germany
[2] Heidelberg Univ, Phys Chem Inst PCI, Heidelberg, Germany
来源：
SOLVENT EXTRACTION AND ION EXCHANGE | 2021年 / 39卷 / 02期
关键词：
actinides; lanthanides; solvent extraction; separation; N-donor;
D O I：
10.1080/07366299.2020.1831235
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A follow up to an earlier review on the coordination and extraction of trivalent actinide and lanthanide ions with triazinylpyridine N-donor ligands is presented. It reviews the recent development in the fields of ligand modifications and improvements, considering both hydrophobic compounds (to be used as extracting agents) and hydrophilic compounds (to be used as stripping agents), with a focus on fundamental studies.
引用
收藏
页码：128 / 151
页数：24
相关论文
共 133 条
[1]   Comparative NMR study of nPrBTP and iPrBTP [J].
Adam, Christian ;
Rohde, Viktoria ;
Muellich, Udo ;
Kaden, Peter ;
Geist, Andreas ;
Panak, Petra J. ;
Geckeis, Horst .
ATALANTE 2016 INTERNATIONAL CONFERENCE ON NUCLEAR CHEMISTRY FOR SUSTAINABLE FUEL CYCLES, 2016, 21 :38-45
[2]   NMR and TRLFS studies of Ln(III) and An(III) C5-BPP complexes [J].
Adam, Christian ;
Beele, Bjoern B. ;
Geist, Andreas ;
Muellich, Udo ;
Kaden, Peter ;
Panak, Petra J. .
CHEMICAL SCIENCE, 2015, 6 (02) :1548-1561
[3]   Evidence for covalence in a N-donor complex of americium(III) [J].
Adam, Christian ;
Kaden, Peter ;
Beele, Bjoern B. ;
Muellich, Udo ;
Trumm, Sascha ;
Geist, Andreas ;
Panak, Petra J. ;
Denecke, Melissa A. .
DALTON TRANSACTIONS, 2013, 42 (39) :14068-14074
[4]   Separation of Am(III), Cm(III) and Eu(III) by electro-spun polystyrene-immobilized CyMe4-BTPhen [J].
Afsar, Ashfaq ;
Westwood, James ;
Distler, Petr ;
Harwood, Laurence M. ;
Mohan, Saeed ;
John, Jan ;
Davis, Frederick J. .
TETRAHEDRON, 2018, 74 (38) :5258-5262
[5]   The Effect of Alkyl Substitution on the Extraction Properties of BTPhen Ligands for the Partitioning of Trivalent Minor Actinides and Lanthanides in Spent Nuclear Fuels [J].
Afsar, Ashfaq ;
Westwood, James ;
Harwood, Laurence M. ;
Hudson, Michael J. ;
Laventine, Dominic M. ;
Geist, Andreas .
JORDAN JOURNAL OF CHEMISTRY, 2014, 9 (01) :50-58
[6]   EFFECTIVE SEPARATION OF Am(III) FROM Cm(III) USING MODIFIED BTPHEN LIGANDS [J].
Afsar, Ashfaq ;
Edwards, Alyn C. ;
Geist, Andreas ;
Harwood, Laurence M. ;
Hudson, Michael J. ;
Westwood, James ;
Whitehead, Roger C. .
HETEROCYCLES, 2017, 95 (01) :575-586
[7]   Effective separation of the actinides Am(III) and Cm(III) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines [J].
Afsar, Ashfaq ;
Harwood, Laurence M. ;
Hudson, Michael J. ;
Westwood, James ;
Geist, Andreas .
CHEMICAL COMMUNICATIONS, 2015, 51 (27) :5860-5863
[8]   Effective separation of Am(III) and Eu(III) from HNO3 solutions using CyMe4-BTPhen-functionalized silica-coated magnetic nanoparticles [J].
Afsar, Ashfaq ;
Harwood, Laurence M. ;
Hudson, Michael J. ;
Distler, Petr ;
John, Jan .
CHEMICAL COMMUNICATIONS, 2014, 50 (95) :15082-15085
[9]   Utilizing electronic effects in the modulation of BTPhen ligands with respect to the partitioning of minor actinides from lanthanides [J].
Afsar, Ashfaq ;
Laventine, Dominic M. ;
Harwood, Laurence M. ;
Hudson, Michael J. ;
Geist, Andreas .
CHEMICAL COMMUNICATIONS, 2013, 49 (76) :8534-8536
[10]   Single Centrifugal Contactor Test of a Proposed Group Actinide Extraction Process for Partitioning and Transmutation Purposes [J].
Aneheim, Emma ;
Ekberg, Christian ;
Modolo, Giuseppe ;
Wilden, Andreas .
SEPARATION SCIENCE AND TECHNOLOGY, 2015, 50 (10) :1554-1559
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