Cu(II), Zn(II) Complexes Containing Calix[4]arene Modified by Salicylaldehyde Acylhydrazone - Synthesis, Properties and Application

被引：0
作者：
Zhang XiaoMei [1 ]
Xu GuoCai [1 ]
Sun JiaLong [2 ]
机构：
[1] Anhui Univ Sci & Technol, Dept Chem & Engn, Huainan, Anhui, Peoples R China
[2] Qingdao Agr Univ, Inst Chem & Pharmaceut, Qingdao, Shandong, Peoples R China
来源：
2011 INTERNATIONAL CONFERENCE ON FUZZY SYSTEMS AND NEURAL COMPUTING (FSNC 2011), VOL III | 2011年
关键词：
salicylaldehyde acylhydrazone calix[4]arene; Cu2+; Zn2+; complex; Zn2+-selective fluorescence probe; PHYSICOCHEMICAL PROPERTIES; SELECTIVE RECOGNITION; CALIXARENE COMPLEXES; FLUORESCENCE; RIM; DERIVATIVES; DINUCLEAR; PENDANTS; CHEMOSENSOR; MONONUCLEAR;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Two complexes L(MAcO)(2) (M=Cu, Zn) containing calix[4]arene ligand H2L modified by salicylaldehyde acylhydrazone have been synthesized and characterized by elemental analysis, MS(ESI), IR, UV-vis and fluorescence. Whereas L(ZnAcO)(2) exhibited an enhancement in fluorescence, the potentiality of H2L acting as a Zn2+-selective fluorescence probe was investigated. Results showed that a good linearity (correlation coefficient 0.999) between fluorescence intensity and concentration of Zn2+ in range of 4.0x10(-6) similar to 4.0x10(-5) mol-L-1 existed in H2L solution of 1.0x10(-4) mol.L-1. The minimum concentration at which H2L could detect Zn2+ was 1.0 x10(-6) mol.L-1. Co-existence of Cu2+, Ni2+ and Mn2+ would interfere the determination of Zn2+, but no influence by Na+, me, Cd2+ and Pb2+.
引用
收藏
页码：266 / 269
页数：4
相关论文
共 50 条
  • [21] Photoluminescence properties of tetrahedral zinc(ii) complexes supported by calix[4]arene-based salicylaldiminato ligands
    Ullmann, Steve
    Schnorr, Rene
    Laube, Christian
    Abel, Bernd
    Kersting, Berthold
    DALTON TRANSACTIONS, 2018, 47 (16) : 5801 - 5811
  • [22] Synthesis and Characterization of Co(II), Ni(II), Cu(II) and Zn(II) Complexes of Glyoxime Hydrazone
    Sarikavakli, N.
    Cakici, H. T.
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (03) : 1321 - 1326
  • [23] Synthesis, DNA binding and anticancer properties of new Cu(II) and Zn(II) complexes of a Schiff base ligand containing a triphenylphosphonium as a lipophilic cation
    Gungor, Ozge
    Gul, Abdulmecit
    Gungor, Seyit Ali
    Comertpay, Sabahattin
    Kose, Muhammet
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2024, 450
  • [24] Sparteine and α-Isosparteine Complexes with Zn(II) and Cu(II): Structure and Spectroscopic Properties
    Jasiewicz, Beata
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2009, 6 (04) : 275 - 282
  • [25] Synthesis and characterization of Ni(II), Cu(II) and Zn(II) complexes with new macrocyclic Schiff base ligands containing piperazine moiety
    Keypour, Hassan
    Arzhangi, Parisa
    Rahpeyma, Nasibeh
    Rezaeivala, Majid
    Elerman, Yalcin
    Buyukgungord, Orhan
    Valencia, Laura
    Khavasi, Hamid Reza
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 977 (1-3) : 6 - 11
  • [26] Synthesis, structures, and property studies on Zn(II), Ni(II), and Cu(II) complexes with a Schiff base ligand containing thiocarbamide group
    Pu Su Zhao
    Hong Yan Wang
    Jie Song
    Lu De Lu
    Structural Chemistry, 2010, 21 : 977 - 987
  • [27] Synthesis, structures, and property studies on Zn(II), Ni(II), and Cu(II) complexes with a Schiff base ligand containing thiocarbamide group
    Zhao, Pu Su
    Wang, Hong Yan
    Song, Jie
    Lu, Lu De
    STRUCTURAL CHEMISTRY, 2010, 21 (05) : 977 - 987
  • [28] Synthesis and characterisation of Ni(II), Cu(II), and Zn(II) complexes with an acyclic Mannich base functionalised with thioglycolate moiety
    Dumbrava, Anca
    Olar, Rodica
    Badea, Mihaela
    Grecu, Maria Nicoleta
    Patrascu, Florentina
    Marutescu, Luminita
    Stanica, Nicolae
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2014, 115 (03) : 2447 - 2455
  • [29] Syntheses, Crystal Structures and DNA-binding Properties of Cd(II), Co(II), Cu(II) and Zn(II) Complexes Containing Imidazolium Derivatives
    Li Yu-Han
    Yang Yu
    Guan Hui-Chao
    Zhang Min
    Xu Lin-Lin
    Yue Shu-Mei
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39 (02) : 356 - 367
  • [30] Synthesis, characterization, and photoluminescence properties of Cu(II), Co(II), Ni(II), and Zn(II) complexes of N-aminopyrimidine-2-thione
    Onal, Zulbiye
    Zengin, Huseyin
    Sonmez, Mehmet
    TURKISH JOURNAL OF CHEMISTRY, 2011, 35 (06) : 905 - 914
12345