Cu(II), Zn(II) Complexes Containing Calix[4]arene Modified by Salicylaldehyde Acylhydrazone - Synthesis, Properties and Application

被引：0
|
作者：
Zhang XiaoMei [1 ]
Xu GuoCai [1 ]
Sun JiaLong [2 ]
机构：
[1] Anhui Univ Sci & Technol, Dept Chem & Engn, Huainan, Anhui, Peoples R China
[2] Qingdao Agr Univ, Inst Chem & Pharmaceut, Qingdao, Shandong, Peoples R China
来源：
2011 INTERNATIONAL CONFERENCE ON FUZZY SYSTEMS AND NEURAL COMPUTING (FSNC 2011), VOL III | 2011年
关键词：
salicylaldehyde acylhydrazone calix[4]arene; Cu2+; Zn2+; complex; Zn2+-selective fluorescence probe; PHYSICOCHEMICAL PROPERTIES; SELECTIVE RECOGNITION; CALIXARENE COMPLEXES; FLUORESCENCE; RIM; DERIVATIVES; DINUCLEAR; PENDANTS; CHEMOSENSOR; MONONUCLEAR;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Two complexes L(MAcO)(2) (M=Cu, Zn) containing calix[4]arene ligand H2L modified by salicylaldehyde acylhydrazone have been synthesized and characterized by elemental analysis, MS(ESI), IR, UV-vis and fluorescence. Whereas L(ZnAcO)(2) exhibited an enhancement in fluorescence, the potentiality of H2L acting as a Zn2+-selective fluorescence probe was investigated. Results showed that a good linearity (correlation coefficient 0.999) between fluorescence intensity and concentration of Zn2+ in range of 4.0x10(-6) similar to 4.0x10(-5) mol-L-1 existed in H2L solution of 1.0x10(-4) mol.L-1. The minimum concentration at which H2L could detect Zn2+ was 1.0 x10(-6) mol.L-1. Co-existence of Cu2+, Ni2+ and Mn2+ would interfere the determination of Zn2+, but no influence by Na+, me, Cd2+ and Pb2+.
引用
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页码：266 / 269
页数：4
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