Study on the fluorescence behavior of p-sulfonated calix[4,6]arene in cationic surfactant cetyltrimethylammonium bromide solution and its analytical application

被引：12

作者：

Zhou, Yunyou ^{[1
]}

Liu, Chun ^{[1
]}

Xu, Hongwei ^{[1
]}

Yu, Huapeng ^{[1
]}

Lu, Qin ^{[1
]}

Wang, Lun ^{[1
]}

机构：

[1] Anhui Normal Univ, Coll Chem & Mat Sci, Anhui Key Lab Funct Mol Solids, Wuhu 241000, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2007年 / 66卷 / 4-5期

基金：

中国国家自然科学基金;

关键词：

p-sulfonated calix[4,6]arene; cationic surfactant; CTAB; complex; fluorescence; ALPHA-AMINO-ACIDS; INCLUSION COMPLEXES; BETA-CYCLODEXTRINS; AMMONIUM CATIONS; RECOGNITION; CALIXARENES; DERIVATIVES; MOLECULES; NMR;

D O I：

10.1016/j.saa.2006.04.031

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The fluorescence properties of p-sulfonated calix[4,6]arene (SCnA, n = 4, 6) in cationic surfactant cetyltrimethylammonium bromide (CTAB) solution were investigated. It was found that the fluorescence intensity of SCnA could be enhanced markedly by an appropriate amount of CTAB. The results indicate the formation of complex between CTAB and SCnA at a 1: 1 complex stoichiometry and their association constants were calculated by applying a deduced equation. Based on the obtained results, a new fluorimetric method has been developed for rapid determination of SCnA with a good linearity in the concentration range of 2 x 10(-7) to 7 x 10(-6) mot L-1. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：919 / 923

页数：5

共 37 条

[1]

Alvarez J., 2001, J SUPRAMOL CHEM, V1, P269, DOI DOI 10.1016/S1472-7862(02)00061-8

[2] Complexation of small neutral organic molecules by water soluble calix[4]arenes [J].